Monitoring and modelling of influent patterns, phase distribution and removal of 20 elements in two primary wastewater treatment plants in Norway

Many small- or medium-sized communities in Northern Europe employ only primary wastewater treatment plants (WWTPs) and effluent discharges can be a relevant source of pollution. The current study combines monitoring and modelling approaches to investigate concentrations, influent patterns, size distribution and removal of 20 elements for the two primary WWTPs (Ladehammeren, LARA; Høvringen, HØRA) serving Trondheim, the third largest city in Norway. Element concentrations were determined in raw influent wastewater, effluents and biosolids, and diurnal inflow patterns were assessed. The elemental distribution in particulate, colloidal and dissolved fractions of untreated wastewater was characterized using filtration separation and electron microscopy. An influent generator model and multivariate statistical analyses were used to determine release patterns and to predict the (co-)occurrence of selected elements. Raw influent wastewater concentrations for most elements were similar in the two WWTPs, with only Ca, Mn, Fe, Co and Ba being significantly higher (p