Green synthesis of zirconium-MOFs
The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction...
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| Veröffentlicht in: | CrystEngComm 2015-01, Vol.17 (22), p.4070-4074 |
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| container_title | CrystEngComm |
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| creator | Reinsch, Helge Bueken, Bart Vermoortele, Frederik Stassen, Ivo Lieb, Alexandra Lillerud, Karl-Petter De Vos, Dirk |
| description | The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction with sulfate anions apparently induces an unusual eightfold connectivity of the Zr cluster. |
| doi_str_mv | 10.1039/C5CE00618J |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2015-01, Vol.17 (22), p.4070-4074 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_cristin_nora_10852_50481 |
| source | NORA - Norwegian Open Research Archives; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Analogue Anions Clusters Fluorination Porosity Sulfates Synthesis Zirconium |
| title | Green synthesis of zirconium-MOFs |
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