Green synthesis of zirconium-MOFs

Green synthesis of zirconium-MOFs

The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction...

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Veröffentlicht in:CrystEngComm 2015-01, Vol.17 (22), p.4070-4074
Hauptverfasser: Reinsch, Helge, Bueken, Bart, Vermoortele, Frederik, Stassen, Ivo, Lieb, Alexandra, Lillerud, Karl-Petter, De Vos, Dirk
Format: Artikel
Sprache:eng
Schlagworte:
Analogue
Anions
Clusters
Fluorination
Porosity
Sulfates
Synthesis
Zirconium
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Beschreibung
Zusammenfassung:The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction with sulfate anions apparently induces an unusual eightfold connectivity of the Zr cluster.
ISSN:1466-8033
1466-8033
DOI:10.1039/C5CE00618J