1H NMR STUDY OF REACTION OF TITANOCENE DICHLORIDE WITH DIMEHYL SULFOXIDE

<正> Tsutsui et al.have studied the reaction of titanocene dichloride (Cp2TiCl2) with dimethyl sulfoxide (DMSO) at 70℃ by means of the 1H NMR method. They thought that a stable complex with Ti-C σ-bond was formed, so that the following reaction took place:

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Veröffentlicht in:科学通报:英文版 1987 (15), p.1031-1036
1. Verfasser: 叶大铿 王成瑞 孟玲芝 刘道玉
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Sprache:eng
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Zusammenfassung:<正> Tsutsui et al.have studied the reaction of titanocene dichloride (Cp2TiCl2) with dimethyl sulfoxide (DMSO) at 70℃ by means of the 1H NMR method. They thought that a stable complex with Ti-C σ-bond was formed, so that the following reaction took place:
ISSN:2095-9273