Product rotational alignment of orbital aligned Ca（1P1） with CnH2n+1Br （n = 1, 2, 3） reactions

Product rotational alignment of orbital aligned Ca（1P1） with CnH2n+1Br （n = 1, 2, 3） reactions

<正> The product rotational alignment of Ca(1P1) with CnH2nBr (n = 1, 2, 3) for different initial Ca(1P1) electronic orbital alignment is probed by means of laser-induced chemiluminescence in beam-gas apparatus And the product rotational alignment of these reactions is calculated with a...

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Veröffentlicht in:自然科学进展：英文版 1996 (3), p.39-46
Hauptverfasser: 杨文胜, 丁国文, 徐大力, 于化忠, 顾月姝, 何国钟, 楼南泉
Format: Artikel
Sprache:eng
Schlagworte:
alignment
beam-gas
laser-induced
chemiluminescence
product
molecular
rotational
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Zusammenfassung:<正> The product rotational alignment of Ca(1P1) with CnH2nBr (n = 1, 2, 3) for different initial Ca(1P1) electronic orbital alignment is probed by means of laser-induced chemiluminescence in beam-gas apparatus And the product rotational alignment of these reactions is calculated with an extended direct interaction with product repulsion (DIPR) model. The effects of the magnitude of the repulsive energy and the reagent approach geometry on the title reactions are also studied.
ISSN:1002-0071