Effect of furan π-bridge on the photovoltaic performance of D-A copolymers based on bi(alkylthio-thienyl)benzodithiophene and fluorobenzotriazole

The medium band gap donor-acceptor (D-A) copolymer J61 based on bi(alkylthio-thienyl)benzodithiophene as donor unit and fluorobenzotriazole as acceptor unit and thiophene as n-bridge has demonstrated excellent photovoltaic performance as donor material in nonfullerene polymer solar cells (PSCs) with...

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Veröffentlicht in:中国科学:化学英文版 2017, Vol.60 (4), p.537-544
1. Verfasser: Tinghai Yan Haijun Bin Yankang Yang Lingwei Xue Zhi-Guo Zhang Yongfang Li
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Sprache:eng
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Zusammenfassung:The medium band gap donor-acceptor (D-A) copolymer J61 based on bi(alkylthio-thienyl)benzodithiophene as donor unit and fluorobenzotriazole as acceptor unit and thiophene as n-bridge has demonstrated excellent photovoltaic performance as donor material in nonfullerene polymer solar cells (PSCs) with narrow bandgap n-type organic semiconductor ITIC as acceptor. For studying the effect of n-bridges on the photovoltaic performance of the D-A copolymers, here we synthesized a new D-A copolymer J61-F based on the same donor and acceptor units as J61 but with furan n-bridges instead of thiophene. J61-F possesses a deeper the highest occupied molecular orbital (HOMO) level at -5.45 eV in comparison with that (-5.32 eV) of J61. The non-fullerene PSCs based on J61-F:ITIC exhibited a maximum power conversion efficiency (PCE) of 8.24% with a higher open-circuit voltage (Voc) of 0.95 V, which is benefitted from the lower-lying HOMO energy level of J61-F donor material. The results indicate that main chain engineering by changing n-bridges is another effective way to tune the electronic energy levels of the conjugated D-A copolymers for the application as donor materials in non-fullerene PSCs.
ISSN:1674-7291
1869-1870