Excellent ethanol sensing properties based on Er2O3-Fe2O3 nanotubes

In this work, pure α-Fe2O3 and Er2O3-Fe2O3 nanotubes were synthesized by a simple single-capillary electrospin- ning technology followed by calcination treatment. The morphologies and crystal structures of the as-prepared samples were characterized by scanning electron microscopy and x-ray diffraction, respectively. The gas-sensing properties of the as-prepared samples have been researched, and the result shows that the Er2O3-Fe2O3 nanotubes exhibit much better sen- sitivity to ethanol. The response value of Er2O3-Fe2O3 nanotubes to 10 ppm ethanol is 21 at the operating temperature 240α, which is 14 times larger than that of pure α-Fe2O3 nanotubes （response value is 1.5）. The ethanol sensing properties of α-Fe2O3 nanotubes are remarkably enhanced by doping Er, and the lowest detection limit of Er2O3-Fe2O3 nanotubes is 300 ppb, to which the response value is about 2. The response and recovery times are about 4 s and 70 s to 10 ppm ethanol, respectively. In addition, the Er2O3-Fe2O3 nanotubes possess good selectivity and long-term stability.