Luminescence and energy transfer of white emittingphosphor YAI3(BO3)4:Ce3+,Dy3

A white emitting phosphor of YAI3(BOa)4:Ce3+, Dy3+is synthesized by a solid state reaction, and its luminescent prop- erties are investigated. Its phase formation is carried out with X-ray powder diffraction analysis, and there is no crys- talline phase other than YAO3(BO3)4. YAI3(BO3)4:Ce3+ can pro...

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Veröffentlicht in:光电子快报:英文版 2015 (2), p.111-115
1. Verfasser: 周芬 王迪 曹鹤英 李净 宋会玲 李盼来 王志军 张坤 庞立斌
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Sprache:eng
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Zusammenfassung:A white emitting phosphor of YAI3(BOa)4:Ce3+, Dy3+is synthesized by a solid state reaction, and its luminescent prop- erties are investigated. Its phase formation is carried out with X-ray powder diffraction analysis, and there is no crys- talline phase other than YAO3(BO3)4. YAI3(BO3)4:Ce3+ can produce 422 nm blue emission under 367 nm excitation. The emission spectrum of YAI3(BO3)4:Dy3+ shows several emission peaks under 350 nm excitation, and the peaks locate at 485 nm, 575 nm and 668 nm, respectively. Emission intensities of Ce3+ and Dy3+ in YAI3(BO3)4 are influenced by their concentrations, and the concentration quenching effect is observed. Energy transfer from Ce3+ to Dy3+ in YAI3(BO3)4 is validated and proved to be a resonant type via a quadrupole-quadrupole interaction, and the emission color can be tuned from blue to white by tuning the ratio of Ce3+/Dy3+. Moreover, the critical distance (Re) of Ce3+ to Dy3+ in YAI3(BO3)4 is calculated to be 1.904 um.
ISSN:1673-1905
1993-5013