Line-profile analysis of excitation spectroscopy in the even 4pS(2p1/2)nl' [K']J (1' = 1,3) autoionizing resonances of Kr

The even-parity autoionizing resonance series 4p^5np' [3/2] 1,2, [ 1/2] 1, and 4p^2nf' [5/213 of krytpon have been investigated by laser excitation from the two metastable states 4p55s [3/2]2 and 4p^55s' [1/2]0 in the photon energy region of 2900(P40000 cm^-1 at experimental bandwidth of -0.1 cm-1....

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Veröffentlicht in:中国科学:化学英文版 2013 (11), p.1623-1632
1. Verfasser: LI ChunYan WANG TingTing ZHEN JunFeng CHEN Yang
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Sprache:eng
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Zusammenfassung:The even-parity autoionizing resonance series 4p^5np' [3/2] 1,2, [ 1/2] 1, and 4p^2nf' [5/213 of krytpon have been investigated by laser excitation from the two metastable states 4p55s [3/2]2 and 4p^55s' [1/2]0 in the photon energy region of 2900(P40000 cm^-1 at experimental bandwidth of -0.1 cm-1. The excitation spectra of the even-parity autoionizing resonance series, most of which are experimentally studied for the first time in this work, show typical asymmetric line shapes. Complementary information on level energies, quantum defects, line profile indices and resonance widths, resonance lifetimes and reduced widths of the auto- ionizing resonances are derived by Fano-type line-shape analyses of the experimental results. Results from this work indicate that the line profile index (q) and the resonance width (F) are approximately proportional to the effective principal quantum number (n*); the line separation of the 4p^5np' autoionizing resonances is also in good agreement with theoretical model
ISSN:1674-7291
1869-1870