Development of Fe(Ⅲ)-containing ether-functionalized imidazolium ionic liquids for aryl Grignard cross-coupling of alkyl halides

A series of Fe(Ⅲ)-containing imidazolium-based ionic liquids containing ether substituents, including [C3OMim][FeCl4] (1, [C3OMim] = 1-(2-methoxyethyl)-3-methylimidazolium), [C3OiPim][FeCl4] (2, [C3OiPim] = 1-isopropyl-3-(2-methoxyethyl) imidazolium), [C3OBim][FeCl4] (3, [C3OBim] = 1-butyl-3-(2-meth...

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Veröffentlicht in:中国科学通报:英文版 2013 (30), p.3624-3629
1. Verfasser: WANG LinLin LU Bing ZHU AiDi SUN HongMei SHEN Qi
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Sprache:eng
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Zusammenfassung:A series of Fe(Ⅲ)-containing imidazolium-based ionic liquids containing ether substituents, including [C3OMim][FeCl4] (1, [C3OMim] = 1-(2-methoxyethyl)-3-methylimidazolium), [C3OiPim][FeCl4] (2, [C3OiPim] = 1-isopropyl-3-(2-methoxyethyl) imidazolium), [C3OBim][FeCl4] (3, [C3OBim] = 1-butyl-3-(2-methoxyethyl)imidazolium), [(C3O)2im][FeCl4] (4, [(C3O)2im] = 1,3-bis(2-methoxyethyl)imidazolium), [C3OMim][FeBr4] (5) and [(C3O)2im][FeBr4] (6), were prepared and characterized by elemental analysis, Raman spectroscopy and electrospray ionization mass spectrometry. The catalytic performances of 1-6 and related Fe(Ⅲ)-based catalysts in the cross-coupling of aryl Grignard reagents with alkyl halides bearing fl-hydrogens were studied, revealing that mono(ether) functionality improves the catalytic activity and that bis(ether) functionality improves the reusability. After simply decanting the product contained in the ethereal layer, complex 4, which containing bis(ether)-functionalized imidaz- olium cation, could be successfully recycled seven times.
ISSN:1001-6538
1861-9541