Manifestation If Substance Molecular Structure in Temperature Effects of Light Scattering
DCMSL (depolarization components of molecular scattering of light) have been studied within the wide spectral range (0-200 cm-1) and in the temperature intervals (20-200 ℃) in toluol (C6HsCH3) and aniline (C6HsNH2). It has been shown that when a liquid is heated and temperatures approach to critical...
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Veröffentlicht in: | 化学与化工:英文版 2013, Vol.7 (8), p.791-795 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | DCMSL (depolarization components of molecular scattering of light) have been studied within the wide spectral range (0-200 cm-1) and in the temperature intervals (20-200 ℃) in toluol (C6HsCH3) and aniline (C6HsNH2). It has been shown that when a liquid is heated and temperatures approach to critical ones, a significant contribution of DCMSL is made by vibration motion of molecules. The special properties of the temperature-frequency behavior of DCMSL spectra are discussed from the view point of hindered rotation of liquid molecules with consideration of intermolecular interaction. |
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ISSN: | 1934-7375 1934-7383 |