SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STAR- SHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE ASCORE
Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studi...
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Veröffentlicht in: | 高分子科学:英文版 2013 (6), p.938-945 |
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Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3. |
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ISSN: | 0256-7679 1439-6203 |