SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STAR- SHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE ASCORE

Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studi...

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Veröffentlicht in:高分子科学:英文版 2013 (6), p.938-945
1. Verfasser: Yang Zou Yuan Liu Jin-gui Qin Chu-luo Yang
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Sprache:eng
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Zusammenfassung:Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.
ISSN:0256-7679
1439-6203