SERGEANTS AND SOLDIERS RULE＂ IN HELICAL SUBSTITUTED- ACETYLENE COPOLYMER EMULSIONS

SERGEANTS AND SOLDIERS RULE＂ IN HELICAL SUBSTITUTED- ACETYLENE COPOLYMER EMULSIONS

The ＂sergeants and soldiers rule＂ occurring in helical copolymer emulsions derived from an achiral monomer （M1） and a chiral monomer （M2） was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show...

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Veröffentlicht in:高分子科学：英文版 2013 (1), p.179-186
1. Verfasser: Xuan Liu CiSong Xiao-feng Luo Wan-tai Yang Jian-ping Deng
Format: Artikel
Sprache:eng
Schlagworte:
UV-Vis光谱
乙炔
共聚物乳液
士兵
手性单体
螺旋式
螺旋结构
透射电子显微镜
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Zusammenfassung:The ＂sergeants and soldiers rule＂ occurring in helical copolymer emulsions derived from an achiral monomer （M1） and a chiral monomer （M2） was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show the （co）polymer chains in the nanoparticles adopt helical structures of a predominant helicity, and the copolymers follow the ＂sergeants and soldiers rule＂ in forming helical structure.
ISSN:0256-7679
1439-6203