源自水稻壳的高比表面纳米二氧化硅负载12-磷钨酸:一种高效纳米催化剂用于几种有机反应(英文)

Nano silica was prepared from rice husk with high surface area.X-ray diffraction(XRD) pattern showed that the amorphous form of silica was produced.Chemical composition of the nano silica was estimated by X-ray fluorescence spectroscopy and CHN analysis.The nano silica was used as a support for H3PW...

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Veröffentlicht in:催化学报 2012, Vol.33 (8), p.1326-1333
1. Verfasser: Ezzat RAFIEE Shabnam SHAHEBRAHIMI
Format: Artikel
Sprache:chi
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Zusammenfassung:Nano silica was prepared from rice husk with high surface area.X-ray diffraction(XRD) pattern showed that the amorphous form of silica was produced.Chemical composition of the nano silica was estimated by X-ray fluorescence spectroscopy and CHN analysis.The nano silica was used as a support for H3PW12O40.The nano silica and nano silica supported H3PW12O40 were characterized by inductively coupled plasma,XRD,transmission electron microscopy(TEM),N2 adsorption-desorption,and Fourier transform infrared spectroscopy.TEM images of nano silica as well as the supported catalyst displayed average size of 6 and 7 nm,respectively.The catalyst showed excellent activity in some important organic reactions including Biginelli,Hantzsch,Mannich,and Claisen-Schmidt reactions with good reusability.Catalytic activity of this nano catalyst is an improvement over the commercially available silica that is used to support H3PW12O40.
ISSN:0253-9837
1872-2067