Frequency Up-conversion Luminescence Properties and Mechanism of Tm~(3+) /Er~(3+)/Yb~(3+) Co-doped Oxyfluorogermanate Glasses

Oxyfluoride glasses were developed with composition 60GeO 2 ·10AlF 3 ·25BaF 2 ·(1.95-x)GdF 3 · 3YbF 3 ·0.05TmF 3 ·xErF 3 (x=0.02,0.05,0.08,0.11,0.14,0.17)in mole percent.Intense blue(476 nm),green(524 and 546 nm)and red(658 nm)emissions which identified from the 1G 4 →3H 6 transition of Tm3+and the(...

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Veröffentlicht in:武汉理工大学学报:材料科学英文版 2011, Vol.26 (3), p.393-397
1. Verfasser: HU Yuebo QIU Jianbei ZHOU Dali SONG Zhiguo YANG Zhengwen
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Sprache:eng
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Zusammenfassung:Oxyfluoride glasses were developed with composition 60GeO 2 ·10AlF 3 ·25BaF 2 ·(1.95-x)GdF 3 · 3YbF 3 ·0.05TmF 3 ·xErF 3 (x=0.02,0.05,0.08,0.11,0.14,0.17)in mole percent.Intense blue(476 nm),green(524 and 546 nm)and red(658 nm)emissions which identified from the 1G 4 →3H 6 transition of Tm3+and the(2H 11/2 ,4S 3/2 )→4I 15/2 ,4F 9/2 →4I 15/2 transitions of Er3+,respectively,were simultaneously observed under 980 nm excitation at room temperature.The results show that multicolor luminescence including white light can be adjustably tuned by changing doping concentrations of Er3+ion or the excitation power.In addition,the energy transfer processes among Tm3+,Er3+and Yb3+ions,and up-conversion mechanisms are discussed.
ISSN:1000-2413
1993-0437