Long-Lasting Phosphorescence Properties of Pyrochlore La2Ti2O7:Pr^3+ Phosphor

The La2Ti2O7:Pr^3+, which emits red color luminescence upon UV light excitation, is prepared by the conventional high-temperature solid-state method and its luminescent properties are systematically investigated. X-ray diffraction, photoluminescence, afterglow emission spectra and long-lasting phosp...

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Veröffentlicht in:Chinese physics letters 2010, Vol.27 (4), p.208-211
1. Verfasser: 褚明辉 蒋大鹏 赵成久 李斌
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Sprache:eng
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Zusammenfassung:The La2Ti2O7:Pr^3+, which emits red color luminescence upon UV light excitation, is prepared by the conventional high-temperature solid-state method and its luminescent properties are systematically investigated. X-ray diffraction, photoluminescence, afterglow emission spectra and long-lasting phosphorescence (LLP) decay curves are used to characterize this phosphor. After irradiation by a 290-nm UV light for 3 rain, the Pr^3+-doped La2Ti2O7 phosphor emits intense red emitting afterglow from the ^1D2 →^ 3H4 transitions, and its afterglow can be seen with the naked eye in the dark clearly for more than 1 h after removal of the excitation source. The afterglow decay curve of the Pr^3+-doped La2Ti2O7 phosphor contains a fast decay component and another slow decay one. The possible mechanism of this red light emitting LLP phosphor is also discussed based on the experimental results.
ISSN:0256-307X
1741-3540