Phase formation with NaZn13 structure in metamagnetic La（Fe1-xCox）11.9Si1.1 compounds

The effects of different annealing conditions on the phase formation with NaZn13 structure were investigated in La（Fe1-xCox）11.9Si1.1 （x=0.068） compounds. It was found that the 1：13 phase was not formed directly from the melt upon cooling but via a peritectic reaction between the pro-peritectic γ-Fe and the La-rich phase. Annealing temperature was very important for the formation of 1：13 phase. Ice water was confirmed to be a preferable quenching medium. La（Fe1-xCox）11.9Si1.1 （x=0.068） compounds with almost single 1：13 phase were obtained at 1473 K after 15 d.