Preparation and Photoluminescent Properties of β-Ga2O3:Dy Nanorod Arrays
β-GaEO3:Dy nanorod arrays were prepared through a hydrothermal process following by a subsequent heat treatment. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and photolumineseenee (PL) spectra were used to characterize the phase, morphology and PL properties of β- Ga...
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Veröffentlicht in: | Journal of rare earths 2005, Vol.23 (5), p.645-645 |
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Sprache: | eng |
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Zusammenfassung: | β-GaEO3:Dy nanorod arrays were prepared through a hydrothermal process following by a subsequent heat treatment. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and photolumineseenee (PL) spectra were used to characterize the phase, morphology and PL properties of β- GaEO3:Dy nanorod arrays. FE-SEM results show that the as-formed hydrothermal products are GaOOH nanorod arrays with the aspect ratio of 3, which construeted from nanorods of 100 nm in diamete and 2 μm in length. The β-GaEO3:Dy nanorod arrays possessing the similar morphology and size with their precursors GaOOH crystal are the final products after 900 ℃ heat treatment. The PL of β-Ga2O3:Dy nanorod arrays consist of two bands, 460 - 505 nm (the maximum 491 nm) and 570 - 600 nm (the maximum 580 nm), which assign to the transitions of Dy^3+ , ^4F9/2-^6H15/2 and ^4F9/2-^6H13/2, respectively. The β-Ga2O3 host lattice could transfer the energy to the Dy^3+ effectively. Compared with the solid state reaction counterparts, β- Ga2O3:Dy nanorod arsays have the more uniform morphology and the higher efficiency of energy transfer. |
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ISSN: | 1002-0721 2509-4963 |