Selective Hydrogenolysis of Glycerol to 1,3-Propanediol Catalyzed by Pt Nanoparticles–AlOx/WO3

Selective Hydrogenolysis of Glycerol to 1,3-Propanediol Catalyzed by Pt Nanoparticles–AlOx/WO3

Tungsten oxide-supported platinum nanoparticles containing aluminum oxide species (Pt–AlOx/WO3) act as a highly efficient heterogeneous catalyst for the hydrogenolysis of glycerol to 1,3-propanediol without any additives. High 1,3-propanediol selectivity was observed due to the concerted effect of t...

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Veröffentlicht in:Chemistry letters 2012-12, Vol.41 (12), p.1720-1722
Hauptverfasser: Mizugaki, Tomoo, Yamakawa, Takayuki, Arundhathi, Racha, Mitsudome, Takato, Jitsukawa, Koichiro, Kaneda, Kiyotomi
Format: Artikel
Sprache:eng
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Zusammenfassung:Tungsten oxide-supported platinum nanoparticles containing aluminum oxide species (Pt–AlOx/WO3) act as a highly efficient heterogeneous catalyst for the hydrogenolysis of glycerol to 1,3-propanediol without any additives. High 1,3-propanediol selectivity was observed due to the concerted effect of the Pt nanoparticles, aluminum oxide, and tungsten oxide support. The Pt–AlOx/WO3 catalyst is reusable with maintaining its high catalytic performance.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2012.1720