Rational Synthetic Strategy for Heterometallic Multinuclear Complexes

Rational Synthetic Strategy for Heterometallic Multinuclear Complexes

A series of heterometallic tetranuclear complexes were developed by the reaction of a ruthenium mononuclear complex, mer-[Ru(Hbpp)3]2+ (Hbpp = 3,5-bis(2-pyridyl)pyrazole), with first-row transition metal ions. The obtained complexes were successfully characterized by ESI TOF-MS, elemental analysis a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2020-02, Vol.49 (2), p.125-128
Hauptverfasser: Izu, Hitoshi, Kondo, Mio, Saga, Yutaka, Iwami, Hikaru, Masaoka, Shigeyuki
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry, Multidisciplinary
Coordination compounds
Crystal structure
Crystals
Physical Sciences
Pyrazole
Ruthenium
Science & Technology
Single crystals
Structural analysis
Transition metals
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A series of heterometallic tetranuclear complexes were developed by the reaction of a ruthenium mononuclear complex, mer-[Ru(Hbpp)3]2+ (Hbpp = 3,5-bis(2-pyridyl)pyrazole), with first-row transition metal ions. The obtained complexes were successfully characterized by ESI TOF-MS, elemental analysis and single crystal X-ray structural analysis. We also discussed the effect of geometrical isomerism of the precursor on the structures of the resulting heterometallic multinuclear complexes.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.190815