Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification

The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallin...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic Chemistry 2016-11, Vol.55 (21), p.10839-10842
Hauptverfasser: Gee, William J., Cadman, Laura K., Amer Hamzah, Harina, Mahon, Mary F., Raithby, Paul R., Burrows, Andrew D.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.
ISSN:1520-510X
0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.6b01917