Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification
The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallin...
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Veröffentlicht in: | Inorganic Chemistry 2016-11, Vol.55 (21), p.10839-10842 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances. |
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ISSN: | 1520-510X 0020-1669 1520-510X |
DOI: | 10.1021/acs.inorgchem.6b01917 |