Transamidation of primary amides with amines catalyzed by zirconocene dichloride

Transamidation of primary amides with amines catalyzed by zirconocene dichloride

Zirconocene dichloride (Cp2ZrCl2) has been shown to be an effective catalyst for the transamidation of primary amides with amines in cyclohexane at 80 °C in 5–24 hours. For favourable substrates, the reaction can be performed at temperatures as low as 30 °C.

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Veröffentlicht in:Chemical Communications 2012-12, Vol.48 (95), p.11626-11628
Hauptverfasser: Atkinson, Benjamin N., Chhatwal, A. Rosie, Lomax, Helen V., Walton, James W., Williams, Jonathan M. J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Zirconocene dichloride (Cp2ZrCl2) has been shown to be an effective catalyst for the transamidation of primary amides with amines in cyclohexane at 80 °C in 5–24 hours. For favourable substrates, the reaction can be performed at temperatures as low as 30 °C.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc37427g