Solid or Liquid ? - Kinetically induced phase transition of a confined liquid
There has been long-standing debate about the physical state and possible phase transformations of confined liquids. In this report we show that a model confined liquid can behave both as a Newtonian liquid with very little change in its dynamics or as a pseudo-solid depending solely on the {\it rat...
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Zusammenfassung: | There has been long-standing debate about the physical state and possible
phase transformations of confined liquids. In this report we show that a model
confined liquid can behave both as a Newtonian liquid with very little change
in its dynamics or as a pseudo-solid depending solely on the {\it rate} of
approach of the confining surfaces. Thus, the confined liquid does {\it not}
exhibit any confinement induced solidification in thermodynamic equilibrium.
Instead, solidification is induced kinetically, when the two confining surfaces
are approached with a minimum critical rate. This critical rate is surprisingly
slow, of the order of 6 \AA /s, explaining the frequent observation of
confinement induced solidification. |
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DOI: | 10.48550/arxiv.cond-mat/0512600 |