Solid or Liquid ? - Kinetically induced phase transition of a confined liquid

There has been long-standing debate about the physical state and possible phase transformations of confined liquids. In this report we show that a model confined liquid can behave both as a Newtonian liquid with very little change in its dynamics or as a pseudo-solid depending solely on the {\it rat...

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Hauptverfasser: Patil, Shivprasad, Matei, George, Oral, Ahmet, Hoffmann, Peter M
Format: Artikel
Sprache:eng
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Zusammenfassung:There has been long-standing debate about the physical state and possible phase transformations of confined liquids. In this report we show that a model confined liquid can behave both as a Newtonian liquid with very little change in its dynamics or as a pseudo-solid depending solely on the {\it rate} of approach of the confining surfaces. Thus, the confined liquid does {\it not} exhibit any confinement induced solidification in thermodynamic equilibrium. Instead, solidification is induced kinetically, when the two confining surfaces are approached with a minimum critical rate. This critical rate is surprisingly slow, of the order of 6 \AA /s, explaining the frequent observation of confinement induced solidification.
DOI:10.48550/arxiv.cond-mat/0512600