Optical response of the bulk stabilized mosaic phase in Se doped TaS$_{2-x}$Se$_{x}
The layered van der Waals material, TaS$_{2}$ features a meta-stable mosaic phase on the verge of a nearly commensurate to commensurate charge density wave transition. This meta-stable or 'hidden' phase can be reached by laser pumping the low temperature, commensurate charge density wave p...
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Zusammenfassung: | The layered van der Waals material, TaS$_{2}$ features a meta-stable mosaic
phase on the verge of a nearly commensurate to commensurate charge density wave
transition. This meta-stable or 'hidden' phase can be reached by laser pumping
the low temperature, commensurate charge density wave phase. Here we report the
stabilization of a bulk, equilibrium mosaic phase in 1T-TaS$_{1.2}$Se$_{0.8}$
single crystals observed with transport and optical spectroscopy experiments.
We identify a bulk pseudogap in the mosaic phase of approximately 200 meV at
the lowest temperatures, while the CCDW phase can be obtained by heating and
instead has a full optical gap of about 100 meV. Surprisingly, a spectral
weight analysis shows that Se doping gives rise to an increased charge density
despite the fact that this is formally an isovalent substitution. This finding
is consistent with the recent observation that the mosaic phase is stabilized
as equilibrium phase through the appearance of charged defects. |
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DOI: | 10.48550/arxiv.2311.15791 |