Exceptionally Slow, Long Range, and Non-Gaussian Critical Fluctuations Dominate the Charge Density Wave Transition
$(TaSe_4)_2I$ is a well-studied quasi-one-dimensional compound long-known to have a charge-density wave (CDW) transition around 263 K. We argue that the critical fluctuations of the pinned CDW order parameter near the transition can be inferred from the resistance noise on account of their coupling...
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Zusammenfassung: | $(TaSe_4)_2I$ is a well-studied quasi-one-dimensional compound long-known to
have a charge-density wave (CDW) transition around 263 K. We argue that the
critical fluctuations of the pinned CDW order parameter near the transition can
be inferred from the resistance noise on account of their coupling to the
dissipative normal carriers. Remarkably, the critical fluctuations of the CDW
order parameter are slow enough to survive the thermodynamic limit and dominate
the low-frequency resistance noise. The noise variance and relaxation time show
rapid growth (critical opalescence and critical slowing down) within a
temperature window of $ \varepsilon \approx \pm 0.1$, where $\varepsilon$ is
the reduced temperature. This is very wide but consistent with the Ginzburg
criterion. We further show that this resistance noise can be quantitatively
used to extract the associated critical exponents. Below $|\varepsilon |
\lesssim 0.02$, we observe a crossover from mean-field to a
fluctuation-dominated regime with the critical exponents taking anomalously low
values. The distribution of fluctuations in the critical transition region is
skewed and strongly non-Gaussian. This non-Gaussianity is interpreted as the
breakdown of the validity of the central limit theorem as the diverging
coherence volume becomes comparable to the macroscopic sample size. The large
magnitude critical fluctuations observed over an extended temperature range, as
well as the crossover from the mean-field to the fluctuation-dominated regime
highlight the role of the quasi-one dimensional character in controlling the
phase transition. |
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DOI: | 10.48550/arxiv.2308.09756 |