Pulse-area theorem for precision control of the rotational motions of a single molecule in a cavity

Journal of Physics A: Mathematical and Theoretical, 2023 We perform a combined analytical and numerical investigation to explore how an analytically designed pulse can precisely control the rotational motions of a single-molecular polariton formed by the strong coupling of two low-lying rotational states with a single-mode cavity. To this end, we derive a pulse-area theorem that gives amplitude and phase conditions of the pulses in the frequency domain for driving the polariton from a given initial state to an arbitrary coherent state. The pulse-area theorem is examined for generating the maximum degree of orientation using a pair of pulses. We show that the phase condition can be satisfied by setting the initial phases of the two identically overlapped pulses or by controlling the time delay between pulses for practical applications.