Designing low-cost TaC virtual substrates for $Al_xGa_{1-x}N$ epitaxy
$Al_xGa_{1-x}N$ is a critical ultra-wide bandgap material for optoelectronics, but the deposition of thick, high quality epitaxial layers has been hindered by a lack of lattice-matched substrates. Here we identify the (111) face of transition metal carbides as a suitable class of materials for subst...
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Zusammenfassung: | $Al_xGa_{1-x}N$ is a critical ultra-wide bandgap material for
optoelectronics, but the deposition of thick, high quality epitaxial layers has
been hindered by a lack of lattice-matched substrates. Here we identify the
(111) face of transition metal carbides as a suitable class of materials for
substrates lattice matched to (0001) $Al_xGa_{1-x}N$ and demonstrate the growth
of thin film TaC which has an effective hexagonal lattice constant matched to
$Al_{0.45}Ga_{0.55}N$. We explore growth conditions for sputtered TaC on
sapphire substrates and investigate the effects of sputter power, layer
thickness and incident plasma angle on film structure and in- and out-of-plane
strain. We then show critical improvements to film quality by annealing films
in a face-to-face configuration at 1600 $^\circ$C, which significantly reduces
full width at half max (FWHM) of in- and out-of-plane diffraction peaks and
results in a step-and-terrace surface morphology. This work presents a path
toward electrically conductive, lattice matched, thermally compatible
substrates for $Al_xGa_{1-x}N$ heteroepitaxy, a critical step for vertical
devices and other power electronics applications. |
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DOI: | 10.48550/arxiv.2208.11769 |