Diffusion coefficient power laws and defect-driven glassy dynamics in swap acceleration

Particle swaps can drastically accelerate dynamics in glass. The mechanism is expected to be vital for a fundamental understanding of glassy dynamics. To extract defining features, we propose a partial swappability with a fraction {\phi_s} of swap-initiating particles, which can only swap locally wi...

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Veröffentlicht in:arXiv.org 2022-10
Hauptverfasser: Gopinath, Gautham, Chun-Shing, Lee, Xin-Yuan, Gao, Xiao-Dong, An, Chan, Chor-Hoi, Cho-Tung, Yip, Hai-Yao Deng, Chi-Hang Lam
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Sprache:eng
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Zusammenfassung:Particle swaps can drastically accelerate dynamics in glass. The mechanism is expected to be vital for a fundamental understanding of glassy dynamics. To extract defining features, we propose a partial swappability with a fraction {\phi_s} of swap-initiating particles, which can only swap locally with each other or with regular particles. We focus on the swap-dominating regime. At all temperatures studied, particle diffusion coefficients scale with {\phi_s} in unexpected power laws with temperature-dependent exponents, consistent with the kinetic picture of glass transition. At small {\phi_s}, swap-initiators, becoming defect particles, induce remarkably typical glassy dynamics of regular particles. This supports defect models of glass.
ISSN:2331-8422
DOI:10.48550/arxiv.2111.11697