Symmetry breaking in single crystal SrTiO$_3$ plates: EPR manifestations

Electron paramagnetic resonance studies of the impurity Fe$^{3+}$ and Mn$^{4+}$ centers indicate that the symmetry of the crystal structure of millimeter-scale strontium titanate plates above 105 K lowers in the bulk from cubic to tetragonal, different from that of the conventional low-temperature a...

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Hauptverfasser: Gabbasov, Bulat F, Gracheva, Irina N, Rodionov, Alexander A, Nikitin, Sergey I, Zverev, Dmitry G, Trepakov, Vladimir A, Dejneka, Alexandr, Jastrabik, Lubomir, Yusupov, Roman V
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Sprache:eng
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Zusammenfassung:Electron paramagnetic resonance studies of the impurity Fe$^{3+}$ and Mn$^{4+}$ centers indicate that the symmetry of the crystal structure of millimeter-scale strontium titanate plates above 105 K lowers in the bulk from cubic to tetragonal, different from that of the conventional low-temperature antiferrodistortive phase. It is shown that the effect does not originate from the residual stress; its magnitude (observed tetragonal distortion) and particular manifestations depend on plate orientation, surface quality and the geometry of a sample. Peculiarities of the observed phenomenon are presented and possible scenario of its realization is discussed.
DOI:10.48550/arxiv.2008.01460