Correlation trends in the hyperfine structure for Rb, Cs, Fr and high-accuracy predictions for hyperfine constants
We have performed high-precision calculations of the hyperfine structure for n 2S_1/2 and n 2P_1/2 states of the alkali-metal atoms Rb, Cs, and Fr across principal quantum number n, and studied the trend in the size of the correlations. Our calculations were performed in the all-orders correlation p...
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Veröffentlicht in: | arXiv.org 2019-07 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | We have performed high-precision calculations of the hyperfine structure for n 2S_1/2 and n 2P_1/2 states of the alkali-metal atoms Rb, Cs, and Fr across principal quantum number n, and studied the trend in the size of the correlations. Our calculations were performed in the all-orders correlation potential method. We demonstrate that the relative correlation corrections fall off quickly with n and tend towards constant and non-zero values for highly-excited states. This trend is supported by experiment, and we utilize the smooth dependence on n to make high-accuracy predictions of the hyperfine constants, with uncertainties to within 0.1% for most states of Rb and Cs. |
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ISSN: | 2331-8422 |
DOI: | 10.48550/arxiv.1907.02657 |