Optical spectroscopy of complex open 4$d$-shell ions Sn$^{7+}$-Sn$^{10+}

Phys. Rev. A 95, 042503 (2017) We analyze the complex level structure of ions with many-valence-electron open [Kr] 4$d^\textrm{m}$ sub-shells ($\textrm{m}$=7-4) with ab initio calculations based on configuration-interaction many-body perturbation theory (CI+MBPT). Charge-state-resolved optical and e...

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Hauptverfasser: Torretti, F, Windberger, A, Ryabtsev, A, Dobrodey, S, Bekker, H, Ubachs, W, Hoekstra, R, Kahl, E. V, Berengut, J. C, López-Urrutia, J. R. Crespo, Versolato, O. O
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Zusammenfassung:Phys. Rev. A 95, 042503 (2017) We analyze the complex level structure of ions with many-valence-electron open [Kr] 4$d^\textrm{m}$ sub-shells ($\textrm{m}$=7-4) with ab initio calculations based on configuration-interaction many-body perturbation theory (CI+MBPT). Charge-state-resolved optical and extreme ultraviolet (EUV) spectra of Sn$^{7+}$-Sn$^{10+}$ ions were obtained using an electron beam ion trap. Semi-empirical spectral fits carried out with the orthogonal parameters technique and Cowan code calculations lead to 90 identifications of magnetic-dipole transitions and the determination of 79 energy ground-configuration levels, questioning some earlier EUV-line assignments. Our results, the most complete data set available to date for these ground configurations, confirm the ab initio predictive power of CI+MBPT calculations for the these complex electronic systems.
DOI:10.48550/arxiv.1612.00747