Optical spectroscopy of complex open 4$d$-shell ions Sn$^{7+}$-Sn$^{10+}
Phys. Rev. A 95, 042503 (2017) We analyze the complex level structure of ions with many-valence-electron open [Kr] 4$d^\textrm{m}$ sub-shells ($\textrm{m}$=7-4) with ab initio calculations based on configuration-interaction many-body perturbation theory (CI+MBPT). Charge-state-resolved optical and e...
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Zusammenfassung: | Phys. Rev. A 95, 042503 (2017) We analyze the complex level structure of ions with many-valence-electron
open [Kr] 4$d^\textrm{m}$ sub-shells ($\textrm{m}$=7-4) with ab initio
calculations based on configuration-interaction many-body perturbation theory
(CI+MBPT). Charge-state-resolved optical and extreme ultraviolet (EUV) spectra
of Sn$^{7+}$-Sn$^{10+}$ ions were obtained using an electron beam ion trap.
Semi-empirical spectral fits carried out with the orthogonal parameters
technique and Cowan code calculations lead to 90 identifications of
magnetic-dipole transitions and the determination of 79 energy
ground-configuration levels, questioning some earlier EUV-line assignments. Our
results, the most complete data set available to date for these ground
configurations, confirm the ab initio predictive power of CI+MBPT calculations
for the these complex electronic systems. |
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DOI: | 10.48550/arxiv.1612.00747 |