Multichannel Quantum Defect Theory for cold molecular collisions

Multichannel Quantum Defect Theory (MQDT) is shown to be capable of producing quantitatively accurate results for low-energy atom-molecule scattering calculations. With a suitable choice of reference potential and short-range matching distance, it is possible to define a matrix that encapsulates the...

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Veröffentlicht in:arXiv.org 2011-08
Hauptverfasser: Croft, James F E, Wallis, Alisdair O G, Hutson, Jeremy M, Julienne, Paul S
Format: Artikel
Sprache:eng
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Zusammenfassung:Multichannel Quantum Defect Theory (MQDT) is shown to be capable of producing quantitatively accurate results for low-energy atom-molecule scattering calculations. With a suitable choice of reference potential and short-range matching distance, it is possible to define a matrix that encapsulates the short-range collision dynamics and is only weakly dependent on energy and magnetic field. Once this has been produced, calculations at additional energies and fields can be performed at a computational cost that is proportional to the number of channels N and not to N^3. MQDT thus provides a promising method for carrying out low-energy molecular scattering calculations on systems where full exploration of the energy- and field-dependence is currently impractical.
ISSN:2331-8422
DOI:10.48550/arxiv.1105.4483