What is the boundary condition for radial wave function of the Schr\"odinger equation ?
Am.J.Phys. 79:668-671,2011 There is much discussion in the mathematical physics literature as well as in quantum mechanics textbooks on spherically symmetric potentials. Nevertheless, there is no consensus about the behavior of the radial function at the origin, particularly for singular potentials....
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Zusammenfassung: | Am.J.Phys. 79:668-671,2011 There is much discussion in the mathematical physics literature as well as in
quantum mechanics textbooks on spherically symmetric potentials. Nevertheless,
there is no consensus about the behavior of the radial function at the origin,
particularly for singular potentials. A careful derivation of the radial
Schr\"odinger equation leads to the appearance of a delta function term when
the Laplace operator is written in spherical coordinates. As a result,
regardless of the behavior of the potential, an additional constraint is
imposed on the radial wave function in the form of a vanishing boundary
condition at the origin. |
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DOI: | 10.48550/arxiv.1009.2694 |