The structure and energetics of $^3$He and $^4$He nanodroplets doped with alkaline earth atoms
We present systematic results, based on density functional calculations, for the structure and energetics of $^3$He and $^4$He nanodroplets doped with alkaline earth atoms. We predict that alkaline earth atoms from Mg to Ba go to the center of $^3$He drops, whereas Ca, Sr, and Ba reside in a deep di...
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Zusammenfassung: | We present systematic results, based on density functional calculations, for
the structure and energetics of $^3$He and $^4$He nanodroplets doped with
alkaline earth atoms. We predict that alkaline earth atoms from Mg to Ba go to
the center of $^3$He drops, whereas Ca, Sr, and Ba reside in a deep dimple at
the surface of $^4$He drops, and Mg is at their center. For Ca and Sr, the
structure of the dimples is shown to be very sensitive to the He-alkaline earth
pair potentials used in the calculations. The $5s5p\leftarrow5s^2$ transition
of strontium atoms attached to helium nanodroplets of either isotope has been
probed in absorption experiments. The spectra show that strontium is solvated
inside $^3$He nanodroplets, supporting the calculations. In the light of our
findings, we emphasize the relevance of the heavier alkaline earth atoms for
analyzing mixed $^3$He-$^4$He nanodroplets, and in particular, we suggest their
use to experimentally probe the $^3$He-$^4$He interface. |
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DOI: | 10.48550/arxiv.0705.1090 |