Palladium on Carbon Encapsulated in POEPOP1500:  A Resin-Supported Catalyst for Hydrogenation Reactions

Palladium on Carbon Encapsulated in POEPOP1500:  A Resin-Supported Catalyst for Hydrogenation Reactions

A new a versatile catalyst for hydrogenation reactions wherein palladium on carbon is encapsulated in POEPOP1500-resin is described. This polymer-supported catalyst has been successfully used in solution phase hydrogenation of a double and a triple bond as well as hydrogenolysis of a benzyl-protecti...

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Veröffentlicht in:Organic letters 2002-01, Vol.4 (1), p.27-30
Hauptverfasser: Jansson, Anita M, Grøtli, Morten, Halkes, Koen M, Meldal, Morten
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container_title Organic letters
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creator Jansson, Anita M
Grøtli, Morten
Halkes, Koen M
Meldal, Morten
description A new a versatile catalyst for hydrogenation reactions wherein palladium on carbon is encapsulated in POEPOP1500-resin is described. This polymer-supported catalyst has been successfully used in solution phase hydrogenation of a double and a triple bond as well as hydrogenolysis of a benzyl-protecting group. While the activity of the new catalyst is marginally lower than standard 10% Pd/C, it has the advantage of being reused several times without significant loss of reactivity.
doi_str_mv 10.1021/ol016812x
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title Palladium on Carbon Encapsulated in POEPOP1500:  A Resin-Supported Catalyst for Hydrogenation Reactions
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