Palladium on Carbon Encapsulated in POEPOP1500: A Resin-Supported Catalyst for Hydrogenation Reactions
A new a versatile catalyst for hydrogenation reactions wherein palladium on carbon is encapsulated in POEPOP1500-resin is described. This polymer-supported catalyst has been successfully used in solution phase hydrogenation of a double and a triple bond as well as hydrogenolysis of a benzyl-protecti...
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| Veröffentlicht in: | Organic letters 2002-01, Vol.4 (1), p.27-30 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A new a versatile catalyst for hydrogenation reactions wherein palladium on carbon is encapsulated in POEPOP1500-resin is described. This polymer-supported catalyst has been successfully used in solution phase hydrogenation of a double and a triple bond as well as hydrogenolysis of a benzyl-protecting group. While the activity of the new catalyst is marginally lower than standard 10% Pd/C, it has the advantage of being reused several times without significant loss of reactivity. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/ol016812x |