The S-Shaped Negative Differential Resistance during the Electrooxidation of H2/CO in Polymer Electrolyte Membrane Fuel Cells: Modeling and Experimental Proof

In the present contribution, the operation of a low temperature polymer electrolyte membrane fuel cell (PEMFC) with H2/CO and N2/CO mixtures is studied. The aim of the work is to clarify a discrepancy between earlier experiments with conventional electrochemical arrangements and experiments carried...

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Veröffentlicht in:Journal of physical chemistry. C 2011-12, Vol.115 (51), p.25315-25329
Hauptverfasser: Kirsch, Sebastian, Hanke-Rauschenbach, Richard, El-Sibai, Ali, Flockerzi, Dietrich, Krischer, Katharina, Sundmacher, Kai
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Sprache:eng
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Zusammenfassung:In the present contribution, the operation of a low temperature polymer electrolyte membrane fuel cell (PEMFC) with H2/CO and N2/CO mixtures is studied. The aim of the work is to clarify a discrepancy between earlier experiments with conventional electrochemical arrangements and experiments carried out with PEMFCs: Investigations of CO oxidation with rotating disk electrode (RDE) setups in acidic electrolytes revealed a hysteresis in the polarization curve around the onset overpotential of CO oxidation, which was not found in PEMFCs so far. The proof of a hysteresis in the PEMFC polarization curve could be interesting in terms of fuel cell performance, because it was argued that its presence also influences the oxidation of H2/CO mixtures. Indeed, in the present work, this hysteresis during operation with a N2/CO mixture is found, but it is seen that it disappears once H2 is added. To understand the background of these studies, a spatially lumped model is derived.
ISSN:1932-7447
1932-7455
DOI:10.1021/jp206660y