Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 6H2O Prussian Blue Analog

Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 6H2O Prussian Blue Analog

To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)6]3− anion into PB architectures in combination with the CoII cation. Herein, we report the first example of a photomagnetic PB analog containing OsIII ions. In a similar vein as the prototypical CoFe PB anal...

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Veröffentlicht in:Journal of the American Chemical Society 2010-09, Vol.132 (38), p.13123-13125
Hauptverfasser: Avendano, Carolina, Hilfiger, Matthew G, Prosvirin, Andrey, Sanders, Codi, Stepien, Darryl, Dunbar, Kim R
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container_end_page 13125
container_issue 38
container_start_page 13123
container_title Journal of the American Chemical Society
container_volume 132
creator Avendano, Carolina
Hilfiger, Matthew G
Prosvirin, Andrey
Sanders, Codi
Stepien, Darryl
Dunbar, Kim R
description To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)6]3− anion into PB architectures in combination with the CoII cation. Herein, we report the first example of a photomagnetic PB analog containing OsIII ions. In a similar vein as the prototypical CoFe PB analogs, this compound exhibits a wide variety of properties including Charge Transfer Induced Spin Transition (CTIST), Temperature Induced Excited Spin State Trapping (TIESST), and magnetic ordering.
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title Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 6H2O Prussian Blue Analog
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