Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 6H2O Prussian Blue Analog
To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)6]3− anion into PB architectures in combination with the CoII cation. Herein, we report the first example of a photomagnetic PB analog containing OsIII ions. In a similar vein as the prototypical CoFe PB anal...
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Veröffentlicht in: | Journal of the American Chemical Society 2010-09, Vol.132 (38), p.13123-13125 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng ; jpn |
Online-Zugang: | Volltext |
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Zusammenfassung: | To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)6]3− anion into PB architectures in combination with the CoII cation. Herein, we report the first example of a photomagnetic PB analog containing OsIII ions. In a similar vein as the prototypical CoFe PB analogs, this compound exhibits a wide variety of properties including Charge Transfer Induced Spin Transition (CTIST), Temperature Induced Excited Spin State Trapping (TIESST), and magnetic ordering. |
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ISSN: | 0002-7863 1520-5126 |
DOI: | 10.1021/ja1041513 |