A High-Nuclearity 3d/4f Metal Oxime Cluster: An Unusual Ni8Dy8 “Core−Shell” Complex from the Use of 2-Pyridinealdoxime

A High-Nuclearity 3d/4f Metal Oxime Cluster: An Unusual Ni8Dy8 “Core−Shell” Complex from the Use of 2-Pyridinealdoxime

The initial employment of 2-pyridinealdoxime in 3d/4f chemistry has led to a NiII 8DyIII 8 cluster with an unprecedented metal topology; the compound has an unusual structure, is the highest-nuclearity metal oxime cluster to date, and exhibits slow magnetization relaxation.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2010-11, Vol.49 (21), p.9743-9745
Hauptverfasser: Papatriantafyllopoulou, Constantina, Stamatatos, Theocharis C, Efthymiou, Constantinos G, Cunha-Silva, Luis, Paz, Filipe A. Almeida, Perlepes, Spyros P, Christou, George
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The initial employment of 2-pyridinealdoxime in 3d/4f chemistry has led to a NiII 8DyIII 8 cluster with an unprecedented metal topology; the compound has an unusual structure, is the highest-nuclearity metal oxime cluster to date, and exhibits slow magnetization relaxation.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic101581g