Oxidation of Alkenes with H2O2 by an in-Situ Prepared Mn(II)/Pyridine-2-carboxylic Acid Catalyst and the Role of Ketones in Activating H2O2

A simple, high yielding catalytic method for the multigram scale selective epoxidation of electron-rich alkenes using near-stoichiometric H2O2 under ambient conditions is reported. The system consists of a Mn(II) salt (

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Veröffentlicht in:ACS catalysis 2012-06, Vol.2 (6), p.1087-1096
Hauptverfasser: Dong, Jia Jia, Saisaha, Pattama, Meinds, Tim G, Alsters, Paul L, Ijpeij, Edwin G, van Summeren, Ruben P, Mao, Bin, Fañanás-Mastral, Martín, de Boer, Johannes W, Hage, Ronald, Feringa, Ben L, Browne, Wesley R
Format: Artikel
Sprache:eng
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Zusammenfassung:A simple, high yielding catalytic method for the multigram scale selective epoxidation of electron-rich alkenes using near-stoichiometric H2O2 under ambient conditions is reported. The system consists of a Mn(II) salt (
ISSN:2155-5435
2155-5435
DOI:10.1021/cs3002226