Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by Rhenium(V) Complexes

Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by Rhenium(V) Complexes

An efficient method for the oxidation of benzylic sp3 C–H bond to produce ketones or esters using rhenium­(V) complexes as catalysts has been developed. Moreover, the amination of benzylic sp3 C–H bond with NH2Ts in the presence of NBS has also been reported in moderate to good yields under the cata...

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Veröffentlicht in:ACS catalysis 2012-01, Vol.2 (1), p.163-167
Hauptverfasser: Peng, Hao, Lin, Aijun, Zhang, Yan, Jiang, Honglai, Zhou, Jiecong, Cheng, Yixiang, Zhu, Chengjian, Hu, Hongwen
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container_end_page 167
container_issue 1
container_start_page 163
container_title ACS catalysis
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creator Peng, Hao
Lin, Aijun
Zhang, Yan
Jiang, Honglai
Zhou, Jiecong
Cheng, Yixiang
Zhu, Chengjian
Hu, Hongwen
description An efficient method for the oxidation of benzylic sp3 C–H bond to produce ketones or esters using rhenium­(V) complexes as catalysts has been developed. Moreover, the amination of benzylic sp3 C–H bond with NH2Ts in the presence of NBS has also been reported in moderate to good yields under the catalyst of rhenium­(V)-based complexes.
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