Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by Rhenium(V) Complexes

An efficient method for the oxidation of benzylic sp3 C–H bond to produce ketones or esters using rhenium(V) complexes as catalysts has been developed. Moreover, the amination of benzylic sp3 C–H bond with NH2Ts in the presence of NBS has also been reported in moderate to good yields under the cata...

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Veröffentlicht in:	ACS catalysis 2012-01, Vol.2 (1), p.163-167
Hauptverfasser:	Peng, Hao, Lin, Aijun, Zhang, Yan, Jiang, Honglai, Zhou, Jiecong, Cheng, Yixiang, Zhu, Chengjian, Hu, Hongwen
Format:	Artikel
Sprache:	eng ; jpn
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	An efficient method for the oxidation of benzylic sp3 C–H bond to produce ketones or esters using rhenium(V) complexes as catalysts has been developed. Moreover, the amination of benzylic sp3 C–H bond with NH2Ts in the presence of NBS has also been reported in moderate to good yields under the catalyst of rhenium(V)-based complexes.
ISSN:	2155-5435 2155-5435
DOI:	10.1021/cs2003577