Cation Gating and Relocation during the Highly Selective “Trapdoor” Adsorption of CO2 on Univalent Cation Forms of Zeolite Rho

Adsorption of CO2 and CH4 has been measured on the Na-, K-, and Cs-forms of zeolite Rho (0–9 bar; 283–333 K). Although CH4 is excluded, CO2 is readily taken up, although the uptake at low pressures decreases strongly, in the order Na+ > K+ > Cs+. Structural studies by powder X-ray diffraction...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry of materials 2014-03, Vol.26 (6), p.2052-2061
Hauptverfasser:	Lozinska, Magdalena M, Mowat, John P. S, Wright, Paul A, Thompson, Stephen P, Jorda, Jose L, Palomino, Miguel, Valencia, Susana, Rey, Fernando
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!