Investigation of a Branchlike MoO3/Polypyrrole Hybrid with Enhanced Electrochemical Performance Used as an Electrode in Supercapacitors

A branchlike MoO3/polypyrrole conductive nanocomposite was facilely prepared by wrapping a homogeneous polypyrrole (PPy) layer around MoO3 nanobelts via the in situ oxidative polymerization of a self-assembled pyrrole monomer. X-ray powder diffraction characterization demonstrated that the PPy polym...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS applied materials & interfaces 2014-01, Vol.6 (2), p.1125-1130
Hauptverfasser: Zhang, Xia, Zeng, Xianzhong, Yang, Min, Qi, Yanxing
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A branchlike MoO3/polypyrrole conductive nanocomposite was facilely prepared by wrapping a homogeneous polypyrrole (PPy) layer around MoO3 nanobelts via the in situ oxidative polymerization of a self-assembled pyrrole monomer. X-ray powder diffraction characterization demonstrated that the PPy polymer does not hinder the crystallization of the MoO3 nanobelts substrate. The electrochemical tests show that the specific capacitance of 129 F g–1 for the MoO3/PPy hybrid is higher than both pristine MoO3 and pure PPy. Moreover, the hybrid electrode with good electrical conductivity displays good cyclic stability of 90% retention after 200 cycles of charge/discharge. These results indicate a promising potential application of the MoO3/PPy nanocomposite for use as an effective electrode material in supercapacitors.
ISSN:1944-8244
1944-8252
DOI:10.1021/am404724u