Investigation of a Branchlike MoO3/Polypyrrole Hybrid with Enhanced Electrochemical Performance Used as an Electrode in Supercapacitors
A branchlike MoO3/polypyrrole conductive nanocomposite was facilely prepared by wrapping a homogeneous polypyrrole (PPy) layer around MoO3 nanobelts via the in situ oxidative polymerization of a self-assembled pyrrole monomer. X-ray powder diffraction characterization demonstrated that the PPy polym...
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Veröffentlicht in: | ACS applied materials & interfaces 2014-01, Vol.6 (2), p.1125-1130 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A branchlike MoO3/polypyrrole conductive nanocomposite was facilely prepared by wrapping a homogeneous polypyrrole (PPy) layer around MoO3 nanobelts via the in situ oxidative polymerization of a self-assembled pyrrole monomer. X-ray powder diffraction characterization demonstrated that the PPy polymer does not hinder the crystallization of the MoO3 nanobelts substrate. The electrochemical tests show that the specific capacitance of 129 F g–1 for the MoO3/PPy hybrid is higher than both pristine MoO3 and pure PPy. Moreover, the hybrid electrode with good electrical conductivity displays good cyclic stability of 90% retention after 200 cycles of charge/discharge. These results indicate a promising potential application of the MoO3/PPy nanocomposite for use as an effective electrode material in supercapacitors. |
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ISSN: | 1944-8244 1944-8252 |
DOI: | 10.1021/am404724u |