Anion-binding catalysis

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Recent highlights in advanced materials

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Anion-Binding Catalysis von Garcia-Mancheno, Olga

Inhaltsangabe: “… Cover -- Title Page -- Copyright -- Contents -- Preface -- List of Abbreviations -- Chapter 1 From Anion Recognition to Organocatalytic Chemical Reactions -- 1.1 Introduction and Background -- 1.1.1 Evolution of Thiourea‐Based Catalysts -- 1.1.2 Evolution of Triazole‐Based Catalysts -- 1.1.3 Progress on Halogen‐Binding‐Based Catalysts -- 1.1.4 Miscellaneous Anion‐Binding Catalysts -- 1.2 Concepts in Anion‐Binding Catalysis -- 1.2.1 Introduction -- 1.2.2 Anion‐Binding Catalysis in Addition Reactions -- 1.2.3 Anion‐Binding Catalysis in Substitution Reactions -- 1.2.4 Anion Binding in Cooperative Catalysis -- 1.2.5 Anion‐Binding in Lewis Acid Enhancement Catalysis -- 1.2.6 Anion‐Binding in Phase Transfer Catalysis -- 1.3 Summary and Outlook -- Acknowledgment -- References -- Chapter 2 Anion Recognition and Binding Constant Determination -- 2.1 Introduction to Supramolecular Chemistry and Binding Constant Determination -- 2.1.1 Chapter Overview -- 2.1.2 Supramolecular Chemistry and Its Connection to Anion‐Assisted Catalysis -- 2.1.3 Brief History of Advances in Supramolecular Anion Binding -- 2.1.4 Predicting the Model of Association and Simulating the Expected Species Distribution Profiles and Binding Curves -- 2.2 Equilibrium Constants, Binding Curves, Titration Conditions, and Errors -- 2.2.1 Physical Origins of Equilibrium Binding Constants -- 2.2.2 Explanation of the Basis for Titration Techniques and Binding Curves -- 2.2.3 Hirose's Rule and Picking the Right Concentration, Solvent, and Technique -- 2.2.4 Error Determination -- 2.3 Experimental Techniques: NMR Spectroscopy -- 2.3.1 When to Use -- 2.3.2 Slow Exchange vs.  …”
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