Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides

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Hauptverfasser: Banys, Juras (VerfasserIn), Dziaugys, Andrius (VerfasserIn), Glukhov, Konstantin E. (VerfasserIn), Morozovska, Anna Nickolaevna 1977- (VerfasserIn), Morozovsky, Nicholas V. (VerfasserIn), Vysochanskii, Yulian M. (VerfasserIn)
Format: Buch
Sprache:English
Veröffentlicht: Weinheim WILEY-VCH [2022]
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Online-Zugang:http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35034-6/
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Datensatz im Suchindex

_version_ 1804184583553417216
adam_text CONTENTS INTRODUCTION XI 1 CRYSTAL STRUCTURE AND PHASE TRANSITIONS IN LAYERED CRYSTALS OF TERNARY PHOSPHOROUS CHALCOGENIDES 1 1.1 FERRIELECTRIC, ANTIFERROELECTRIC, AND MODULATED ORDERINGS IN MM PX, (M - CU, AG; M - IN, BI; X - S, SE) 1 1.2 RELAXOR AND DIPOLE GLASSY STATES ON THE PHASE DIAGRAM OF CUINP2(SE,S-)6 MIXED CRYSTALS 3 1.2.1 1.2.2 1.2.3 1.2.4 XRD INVESTIGATIONS OF CUINP 2 SE 6 4 RELAXOR PHASE IN MIXED CUINP2(S,SE,-X) CRYSTALS 7 DIPOLAR GLASS PHASE IN MIXED CUINP2(S,SE,-X) CRYSTALS 10 INFLUENCE OF A SMALL AMOUNT OF SELENIUM TO PHASE-TRANSITION DYNAMICS IN CUINP 2 S 6 CRYSTALS 12 1.2.5 1.3 PHASE DIAGRAM 13 ANTIFERROMAGNETIC ORDERING AND ANISOTROPY OF MAGNETIZATION IN MULTIFERROICS CU(IN,-YYCR,)PS 15 1.3.1 1.3.2 TEMPERATURE DEPENDENCE OF THE MAGNETIZATION 17 FIELD DEPENDENCE OF THE MAGNETIZATION AND ANISOTROPY OF MAGNETIZATION AND SUSCEPTIBILITY 19 1.4 1.5 MAGNETIC ORDERING IN MN 2 P 2 S 6 CRYSTAL 21 POLAR LAYERED CRYSTALS OF SNP 2 S 6 TYPE 30 REFERENCES 34 2 2.1 2.2 ELECTRONIC BAND STRUCTURE 41 CHEMICAL BONDING IN P 2 S(SE) 6 STRUCTURAL GROUPS 41 HYBRIDIZATION OF THE ELECTRONIC VALENCE ORBITALS AND STRUCTURAL STABILITY OF MM P 2 S(SE) 6 -TYPE COMPOUNDS 43 2.3 SECOND-ORDER JAHN-TELLER EFFECT AND DIPOLE ORDERING IN CU(AG)INP 2 S(SE) 6 CRYSTALS WITH D 10 CU + AND AG + CATIONS 63 2.4 SECOND-ORDER JAHN-TELLER EFFECT AND PHASE TRANSITIONS IN CU(AG)BIP 2 S(SE) 6 CRYSTALS WITH A STEREOACTIVE ELECTRONIC LONE PAIR OF BI 3+ 79 REFERENCES 85 VI CONTENTS 3 3.1 3.2 OPTICAL PROPERTIES OF MM P2S(SE)6 CRYSTALS 95 DFT CALCULATED ELECTRONIC BAND STRUCTURES AND OPTICAL PARAMETERS 95 TEMPERATURE DEPENDENCE OF THE OPTICAL ABSORPTION FOR MN P2S6, AGINP,S, CUINP 2 S(SE) 6 , AND CUCRP 2 S 6 , SNP 2 S 6 LAYERED CRYSTALS 103 3.3 APPEARANCE OF DIPOLE GLASSY STATE IN THE EDGE OPTICAL ABSORPTION OF CUINP2(SE,S,-)6 MIXED CRYSTALS 121 REFERENCES 127 4 4.1 4.2 PHONON SPECTRA OF LAYERED MM P 2 S(SE) 6 CRYSTALS 131 DFT CALCULATED PHONON SPECTRA IN DIFFERENT PHASES 131 RAMAN SPECTROSCOPY OF CUINP 2 S 6 CRYSTAL ACROSS FERRIELECTRIC PHASE TRANSITION 144 4.3 4.4 PHONON SPECTRA OF CUINP2(SE,S- ) MIXED CRYSTALS 151 ANISOTROPY OF THERMAL CONDUCTIVITY TEMPERATURE DEPENDENCE IN CU(AG)IN(BI)P 2 S(SE) 6 LAYERED CRYSTALS 160 4.5 HEAT CAPACITY ANOMALIES AT DIPOLE AND MAGNETIC ORDERING IN CUINP 2 S(SE) 6 AND CUCRP 2 S 6 CRYSTALS 180 4.6 SPIN-PHONON COUPLING IN MN 2 P 2 S 6 CRYSTAL 186 REFERENCES 196 5 SEMICONDUCTOR TO METAL TRANSITIONS IN SNP2S - AND SN 2 P 2 S 6-TYPE COMPOUNDS 201 5.1 LAYERED GEP 2 S 6 , GEP 2 SE 6 , GEP 2 TE 6 , SNP 2 S 6 , SNP 2 SE 6 , AND SNP 2 TE 6 POLAR CRYSTALS WITH PRESSURE OR CHEMICAL COMPOSITION-INDUCED SEMICONDUCTOR-METAL TRANSITION 201 5.2 5.3 PRESSURE-INDUCED METAL STATE IN SN 2 P 2 S 6 AND SN 2 P 2 SE 6 COMPOUNDS 208 DFT CALCULATED TRANSFORMATION OF ELECTRON AND PHONON SPECTRA AT TRANSITION INTO POLAR METAL STATE 211 REFERENCES 220 6 DIELECTRIC AND FERROELECTRIC PROPERTIES OF LAYERED PHOSPHORUS CHALCOGENIDE CRYSTALS 223 6.1 ANISOTROPY EFFECTS IN THICK-LAYERED CUINP 2 S 6 AND CUINP 2 SE 6 CRYSTALS 223 6.2 6.2.1 6.2.2 6.2.3 6.2.4 6.3 DIPOLE GLASS STATE IN CU(IN,CR-Y)P,SG CRYSTALS 226 PHASE TRANSITIONS IN CUCRP 2 S 6 AND CULN O 1 CR 0 9 P 2 S 6 CRYSTALS 227 INHOMOGENEOUS FERRIELECTRICS 228 DIPOLE GLASS STATE IN MIXED CULN,CR-XPS CRYSTALS 234 PHASE DIAGRAM OF THE MIXED CUIN X CR 1 _ X P 2 S 6 CRYSTALS 236 NONLINEAR DIELECTRIC RESPONSE OF LAYERED (AG,CU)(IN,CR)P 2 S 6 CRYSTALS 237 6.4 6.4.1 6.4.2 DIELECTRIC SPECTROSCOPY OF CUBIP 2 SE 6 CRYSTALS 244 ANTIFERROELECTRIC PHASE TRANSITION 244 FREEZING PHENOMENA 246 REFERENCES 248 CONTENTS VII 7 IONIC CONDUCTIVITY AND LOW-FREQUENCY NOISE SPECTROSCOPIC STUDIES 251 7.1 IONIC CONDUCTIVITY INVESTIGATIONS IN CUINP 2 S 6 AND CUIN,+ZP2S, CRYSTALS 251 7.2 CONDUCTIVITY SPECTROSCOPY OF AGINP2(SE,S-)6 AND (CU,AG,-)CRP,S, CRYSTALS 252 7.3 7.3.1 7.3.2 7.3.3 7.3.4 LOW-FREQUENCY NOISE SPECTROSCOPY OF LAYERED CUINP 2 S 6 253 INTRINSIC NOISE TYPES 254 EXPERIMENTAL TECHNIQUES FOR NOISE DETERMINATION 255 NOISE SPECTROSCOPY IN MATERIALS SCIENCE 256 BRIEF OVERVIEW OF LOW-FREQUENCY NOISE SPECTROSCOPIC STUDIES OF CUINP 2 S 6 256 7.4 ELECTRICAL CONDUCTIVITY OF LAYERED CUINP (S,SE,-X) CRYSTALS 258 REFERENCES 259 8 ULTRASONIC AND PIEZOELECTRIC STUDIES OF PHASE TRANSITIONS IN TWO-DIMENSIONAL CULNP 2 S 6 -TYPE CRYSTALS 263 8.1 8.2 ULTRASONIC INVESTIGATION OF PHASE TRANSITION IN CUINP 2 S 6 CRYSTALS 263 PIEZOELECTRIC AND ULTRASONIC INVESTIGATIONS OF MIXED (AG,CU)INP 2 (S,SE) 6 LAYERED CRYSTALS 265 8.3 ULTRASONIC SPECTROSCOPY OF QUASI TWO-DIMENSIONAL CUINP2(SE,S1- ) MIXED CRYSTALS 268 8.4 PIEZOELECTRIC AND ELASTIC PROPERTIES OF LAYERED MATERIALS OF CU(IN,CR)P 2 (S,SE) 6 SYSTEM 270 REFERENCES 272 9 NANO SCALE INVESTIGATIONS, DOMAIN STRUCTURE, AND SWITCHING PROCESSES OF LOW-DIMENSIONAL FERROELECTRIC LAYERED CHALCOGENIDES 275 9.1 9.2 9.3 FERRIELECTRIC STATE IN FEW LAYER OR MONOLAYER CUINP 2 S 6 SAMPLES 275 BRIGHT DOMAIN WALLS IN CUINP 2 SE 6 CRYSTALS 283 ANTISITE DEFECTS IN LAYERED MULTIFERROIC CUCR 0 9 IN 0 1P2S 287 REFERENCES 291 10 PHENOMENOLOGICAL DESCRIPTION OF SOFT PHONON SPECTRA, PHASE DIAGRAMS, AND DOMAIN MORPHOLOGY OF LOW-DIMENSIONAL FERROELECTRIC LAYERED CHALCOGENIDES 295 10.1 10.2 BRIEF OVERVIEW 295 SPATIALLY MODULATED INCOMMENSURATE PHASES AND SOFT PHONON DISPERSION IN FERROELECTRIC LAYERED CHALCOGENIDES 296 10.2.1 LANDAU-GINZBURG-DEVONSHIRE-FREE ENERGY FUNCTIONAL AND LAGRANGE FUNCTION 297 10.2.2 THE STABILITY OF SPATIALLY MODULATED PHASES IN FERROELECTRIC CHALCOGENIDES 301 10.2.3 ANALYTICAL DESCRIPTION OF THE SOFT PHONON DISPERSION 302 VIII CONTENTS 10.2.4 10.2.5 ANALYSIS OF THE CRITICAL POINTS IN THE SOFT PHONON SPECTRA 305 THE BEHAVIOR OF SOFT ACOUSTIC PHONONS IN THE VICINITY OF CRITICAL WAVE VECTORS 306 10.2.6 10.2.7 ELASTIC SOFTENING OF THE SOUND VELOCITY 307 SOFT PHONON DISPERSION IN FERROELECTRIC CHALCOGENIDES: COMPARISON WITH EXPERIMENT 308 10.2.8 10.3 TEMPERATURE DEPENDENCE OF STATIC DIELECTRIC SUSCEPTIBILITY 309 PHASE DIAGRAMS WITH INCOMMENSURATE PHASES AND DOMAIN SPLITTING IN THIN FILMS OF FERROELECTRIC LAYERED CHALCOGENIDES 311 10.3.1 APPROXIMATE ANALYTICAL SOLUTION OF THE LINEARIZED EULER-LAGRANGE EQUATIONS 313 10.3.2 10.4 PHASE EQUILIBRIUM AND DOMAIN STRUCTURE TEMPERATURE EVOLUTION 314 PHENOMENOLOGICAL DESCRIPTION OF PHASE DIAGRAMS AND COMPLEX DOMAIN MORPHOLOGY OF FERROELECTRIC LAYERED CHALCOGENIDE NANOPARTICLES 317 10.4.1 RECONSTRUCTION OF CIPS THERMODYNAMIC POTENTIAL FROM EXPERIMENTS 318 10.4.2 10.4.3 TEMPERATURE-STRESS PHASE DIAGRAMS OF BULK CUINP 2 S 6 319 THE STRESS-INDUCED PHASE TRANSITIONS IN CUINP 2 S 6 NANOPARTICLES OF DIFFERENT SHAPES 322 10.4.4 10.4.5 LABYRINTHINE DOMAINS IN CIPS NANOPARTICLES 325 ANALYTICAL DESCRIPTION OF COMPLEX DOMAIN MORPHOLOGY IN FERROELECTRIC LAYERED CHALCOGENIDE NANOPARTICLES 327 10.5 PHENOMENOLOGICAL DESCRIPTION OF BRIGHT-CONTRAST AND DARK-CONTRAST DOMAIN WALLS IN FERROELECTRIC-ANTIFERROELECTRIC LAYERED CHALCOGENIDES 332 10.5.1 10.5.2 10.5.3 10.5.4 10.6 10.A 10.B LGD-FSM APPROACH 332 PHASE DIAGRAMS OF THE ORDER PARAMETERS 335 BRIGHT AND DARK DOMAIN WALLS 337 COMPARISON WITH EXPERIMENT 339 CONCLUSIONS 341 APPENDIX A: ANALYTICAL EXPRESSIONS FOR THE SOFT PHONON FREQUENCY 342 APPENDIX B: SOFT ACOUSTIC MODE BEHAVIOR IN THE VICINITY OF CRITICAL WAVE VECTORS 345 10.C APPENDIX C: TEMPERATURE DEPENDENCE OF THE STATIC DIELECTRIC SUSCEPTIBILITY 346 10.D APPENDIX D: DERIVATION OF PE-SDFE TRANSITION TEMPERATURE FOR SPHERICAL NANOPARTICLES 347 10.E APPENDIX E: DERIVATION OF PE-PDFE TRANSITION TEMPERATURE FOR SPHERICAL NANOPARTICLES 349 REFERENCES 352 11 APPLICATION EXAMPLES OF FERROELECTRIC 2D LAYERED INDIUM COPPER THIOPHOSPHATE CHALCOGENIDE, CULNP 2 S 6 359 11.1 THE FERROELECTRIC (FE) FAMILY OF METAL (M) HYPO(TIO/SELENO)DIPHOSPHATES 359 CONTENTS IX 11.2 PIEZOELECTRIC AND PYROELECTRIC ACTIVITY AND ELECTROCALORIC EFFECTIVITY OF CUINP 2 S 6 NANOFLAKES 360 11.2.1 11.2.2 11.2.3 11.3 PIEZOACTIVITY OF CUINP 2 S 6 NANOFLAKES 360 PYROACTIVITY OF CUINP 2 S 6 NANOFLAKES 360 ELECTROCALORIC PERFORMANCES OF CUINP 2 S 6 NANOFLAKES 361 PROMISES OF 2D LAYERED CUINP 2 S 6 FOR FERROELECTRIC FIELD EFFECT TRANSISTORS AND MEMORY APPLICATIONS 361 11.3.1 11.3.2 11.3.3 THEORETICAL CONSIDERATIONS AND EVALUATIONS 362 EXPERIMENTAL INVESTIGATIONS AND PROPOSITIONS 362 NEGATIVE CAPACITANCE FIELD EFFECT TRANSISTORS BASED ON TWO-DIMENSIONAL VAN DER WAALS HETEROSTRUCTURES 364 11.4 CONCLUSIONS 365 REFERENCES 366 INDEX 371
adam_txt CONTENTS INTRODUCTION XI 1 CRYSTAL STRUCTURE AND PHASE TRANSITIONS IN LAYERED CRYSTALS OF TERNARY PHOSPHOROUS CHALCOGENIDES 1 1.1 FERRIELECTRIC, ANTIFERROELECTRIC, AND MODULATED ORDERINGS IN MM ' PX, (M - CU, AG; M' - IN, BI; X - S, SE) 1 1.2 RELAXOR AND DIPOLE GLASSY STATES ON THE PHASE DIAGRAM OF CUINP2(SE,S-)6 MIXED CRYSTALS 3 1.2.1 1.2.2 1.2.3 1.2.4 XRD INVESTIGATIONS OF CUINP 2 SE 6 4 RELAXOR PHASE IN MIXED CUINP2(S,SE,-X) CRYSTALS 7 DIPOLAR GLASS PHASE IN MIXED CUINP2(S,SE,-X) CRYSTALS 10 INFLUENCE OF A SMALL AMOUNT OF SELENIUM TO PHASE-TRANSITION DYNAMICS IN CUINP 2 S 6 CRYSTALS 12 1.2.5 1.3 PHASE DIAGRAM 13 ANTIFERROMAGNETIC ORDERING AND ANISOTROPY OF MAGNETIZATION IN MULTIFERROICS CU(IN,-YYCR,)PS 15 1.3.1 1.3.2 TEMPERATURE DEPENDENCE OF THE MAGNETIZATION 17 FIELD DEPENDENCE OF THE MAGNETIZATION AND ANISOTROPY OF MAGNETIZATION AND SUSCEPTIBILITY 19 1.4 1.5 MAGNETIC ORDERING IN MN 2 P 2 S 6 CRYSTAL 21 POLAR LAYERED CRYSTALS OF SNP 2 S 6 TYPE 30 REFERENCES 34 2 2.1 2.2 ELECTRONIC BAND STRUCTURE 41 CHEMICAL BONDING IN P 2 S(SE) 6 STRUCTURAL GROUPS 41 HYBRIDIZATION OF THE ELECTRONIC VALENCE ORBITALS AND STRUCTURAL STABILITY OF MM'P 2 S(SE) 6 -TYPE COMPOUNDS 43 2.3 SECOND-ORDER JAHN-TELLER EFFECT AND DIPOLE ORDERING IN CU(AG)INP 2 S(SE) 6 CRYSTALS WITH D 10 CU + AND AG + CATIONS 63 2.4 SECOND-ORDER JAHN-TELLER EFFECT AND PHASE TRANSITIONS IN CU(AG)BIP 2 S(SE) 6 CRYSTALS WITH A STEREOACTIVE ELECTRONIC LONE PAIR OF BI 3+ 79 REFERENCES 85 VI CONTENTS 3 3.1 3.2 OPTICAL PROPERTIES OF MM ' P2S(SE)6 CRYSTALS 95 DFT CALCULATED ELECTRONIC BAND STRUCTURES AND OPTICAL PARAMETERS 95 TEMPERATURE DEPENDENCE OF THE OPTICAL ABSORPTION FOR MN P2S6, AGINP,S, CUINP 2 S(SE) 6 , AND CUCRP 2 S 6 , SNP 2 S 6 LAYERED CRYSTALS 103 3.3 APPEARANCE OF DIPOLE GLASSY STATE IN THE EDGE OPTICAL ABSORPTION OF CUINP2(SE,S,-)6 MIXED CRYSTALS 121 REFERENCES 127 4 4.1 4.2 PHONON SPECTRA OF LAYERED MM'P 2 S(SE) 6 CRYSTALS 131 DFT CALCULATED PHONON SPECTRA IN DIFFERENT PHASES 131 RAMAN SPECTROSCOPY OF CUINP 2 S 6 CRYSTAL ACROSS FERRIELECTRIC PHASE TRANSITION 144 4.3 4.4 PHONON SPECTRA OF CUINP2(SE,S- ) MIXED CRYSTALS 151 ANISOTROPY OF THERMAL CONDUCTIVITY TEMPERATURE DEPENDENCE IN CU(AG)IN(BI)P 2 S(SE) 6 LAYERED CRYSTALS 160 4.5 HEAT CAPACITY ANOMALIES AT DIPOLE AND MAGNETIC ORDERING IN CUINP 2 S(SE) 6 AND CUCRP 2 S 6 CRYSTALS 180 4.6 SPIN-PHONON COUPLING IN MN 2 P 2 S 6 CRYSTAL 186 REFERENCES 196 5 SEMICONDUCTOR TO METAL TRANSITIONS IN SNP2S - AND SN 2 P 2 S 6-TYPE COMPOUNDS 201 5.1 LAYERED GEP 2 S 6 , GEP 2 SE 6 , GEP 2 TE 6 , SNP 2 S 6 , SNP 2 SE 6 , AND SNP 2 TE 6 POLAR CRYSTALS WITH PRESSURE OR CHEMICAL COMPOSITION-INDUCED SEMICONDUCTOR-METAL TRANSITION 201 5.2 5.3 PRESSURE-INDUCED METAL STATE IN SN 2 P 2 S 6 AND SN 2 P 2 SE 6 COMPOUNDS 208 DFT CALCULATED TRANSFORMATION OF ELECTRON AND PHONON SPECTRA AT TRANSITION INTO POLAR METAL STATE 211 REFERENCES 220 6 DIELECTRIC AND FERROELECTRIC PROPERTIES OF LAYERED PHOSPHORUS CHALCOGENIDE CRYSTALS 223 6.1 ANISOTROPY EFFECTS IN THICK-LAYERED CUINP 2 S 6 AND CUINP 2 SE 6 CRYSTALS 223 6.2 6.2.1 6.2.2 6.2.3 6.2.4 6.3 DIPOLE GLASS STATE IN CU(IN,CR-Y)P,SG CRYSTALS 226 PHASE TRANSITIONS IN CUCRP 2 S 6 AND CULN O 1 CR 0 9 P 2 S 6 CRYSTALS 227 INHOMOGENEOUS FERRIELECTRICS 228 DIPOLE GLASS STATE IN MIXED CULN,CR-XPS CRYSTALS 234 PHASE DIAGRAM OF THE MIXED CUIN X CR 1 _ X P 2 S 6 CRYSTALS 236 NONLINEAR DIELECTRIC RESPONSE OF LAYERED (AG,CU)(IN,CR)P 2 S 6 CRYSTALS 237 6.4 6.4.1 6.4.2 DIELECTRIC SPECTROSCOPY OF CUBIP 2 SE 6 CRYSTALS 244 ANTIFERROELECTRIC PHASE TRANSITION 244 FREEZING PHENOMENA 246 REFERENCES 248 CONTENTS VII 7 IONIC CONDUCTIVITY AND LOW-FREQUENCY NOISE SPECTROSCOPIC STUDIES 251 7.1 IONIC CONDUCTIVITY INVESTIGATIONS IN CUINP 2 S 6 AND CUIN,+ZP2S, CRYSTALS 251 7.2 CONDUCTIVITY SPECTROSCOPY OF AGINP2(SE,S-)6 AND (CU,AG,-)CRP,S, CRYSTALS 252 7.3 7.3.1 7.3.2 7.3.3 7.3.4 LOW-FREQUENCY NOISE SPECTROSCOPY OF LAYERED CUINP 2 S 6 253 INTRINSIC NOISE TYPES 254 EXPERIMENTAL TECHNIQUES FOR NOISE DETERMINATION 255 NOISE SPECTROSCOPY IN MATERIALS SCIENCE 256 BRIEF OVERVIEW OF LOW-FREQUENCY NOISE SPECTROSCOPIC STUDIES OF CUINP 2 S 6 256 7.4 ELECTRICAL CONDUCTIVITY OF LAYERED CUINP (S,SE,-X) CRYSTALS 258 REFERENCES 259 8 ULTRASONIC AND PIEZOELECTRIC STUDIES OF PHASE TRANSITIONS IN TWO-DIMENSIONAL CULNP 2 S 6 -TYPE CRYSTALS 263 8.1 8.2 ULTRASONIC INVESTIGATION OF PHASE TRANSITION IN CUINP 2 S 6 CRYSTALS 263 PIEZOELECTRIC AND ULTRASONIC INVESTIGATIONS OF MIXED (AG,CU)INP 2 (S,SE) 6 LAYERED CRYSTALS 265 8.3 ULTRASONIC SPECTROSCOPY OF QUASI TWO-DIMENSIONAL CUINP2(SE,S1- ) MIXED CRYSTALS 268 8.4 PIEZOELECTRIC AND ELASTIC PROPERTIES OF LAYERED MATERIALS OF CU(IN,CR)P 2 (S,SE) 6 SYSTEM 270 REFERENCES 272 9 NANO SCALE INVESTIGATIONS, DOMAIN STRUCTURE, AND SWITCHING PROCESSES OF LOW-DIMENSIONAL FERROELECTRIC LAYERED CHALCOGENIDES 275 9.1 9.2 9.3 FERRIELECTRIC STATE IN FEW LAYER OR MONOLAYER CUINP 2 S 6 SAMPLES 275 BRIGHT DOMAIN WALLS IN CUINP 2 SE 6 CRYSTALS 283 ANTISITE DEFECTS IN LAYERED MULTIFERROIC CUCR 0 9 IN 0 1P2S 287 REFERENCES 291 10 PHENOMENOLOGICAL DESCRIPTION OF SOFT PHONON SPECTRA, PHASE DIAGRAMS, AND DOMAIN MORPHOLOGY OF LOW-DIMENSIONAL FERROELECTRIC LAYERED CHALCOGENIDES 295 10.1 10.2 BRIEF OVERVIEW 295 SPATIALLY MODULATED INCOMMENSURATE PHASES AND SOFT PHONON DISPERSION IN FERROELECTRIC LAYERED CHALCOGENIDES 296 10.2.1 LANDAU-GINZBURG-DEVONSHIRE-FREE ENERGY FUNCTIONAL AND LAGRANGE FUNCTION 297 10.2.2 THE STABILITY OF SPATIALLY MODULATED PHASES IN FERROELECTRIC CHALCOGENIDES 301 10.2.3 ANALYTICAL DESCRIPTION OF THE SOFT PHONON DISPERSION 302 VIII CONTENTS 10.2.4 10.2.5 ANALYSIS OF THE CRITICAL POINTS IN THE SOFT PHONON SPECTRA 305 THE BEHAVIOR OF SOFT ACOUSTIC PHONONS IN THE VICINITY OF CRITICAL WAVE VECTORS 306 10.2.6 10.2.7 ELASTIC SOFTENING OF THE SOUND VELOCITY 307 SOFT PHONON DISPERSION IN FERROELECTRIC CHALCOGENIDES: COMPARISON WITH EXPERIMENT 308 10.2.8 10.3 TEMPERATURE DEPENDENCE OF STATIC DIELECTRIC SUSCEPTIBILITY 309 PHASE DIAGRAMS WITH INCOMMENSURATE PHASES AND DOMAIN SPLITTING IN THIN FILMS OF FERROELECTRIC LAYERED CHALCOGENIDES 311 10.3.1 APPROXIMATE ANALYTICAL SOLUTION OF THE LINEARIZED EULER-LAGRANGE EQUATIONS 313 10.3.2 10.4 PHASE EQUILIBRIUM AND DOMAIN STRUCTURE TEMPERATURE EVOLUTION 314 PHENOMENOLOGICAL DESCRIPTION OF PHASE DIAGRAMS AND COMPLEX DOMAIN MORPHOLOGY OF FERROELECTRIC LAYERED CHALCOGENIDE NANOPARTICLES 317 10.4.1 RECONSTRUCTION OF CIPS THERMODYNAMIC POTENTIAL FROM EXPERIMENTS 318 10.4.2 10.4.3 TEMPERATURE-STRESS PHASE DIAGRAMS OF BULK CUINP 2 S 6 319 THE STRESS-INDUCED PHASE TRANSITIONS IN CUINP 2 S 6 NANOPARTICLES OF DIFFERENT SHAPES 322 10.4.4 10.4.5 LABYRINTHINE DOMAINS IN CIPS NANOPARTICLES 325 ANALYTICAL DESCRIPTION OF COMPLEX DOMAIN MORPHOLOGY IN FERROELECTRIC LAYERED CHALCOGENIDE NANOPARTICLES 327 10.5 PHENOMENOLOGICAL DESCRIPTION OF BRIGHT-CONTRAST AND DARK-CONTRAST DOMAIN WALLS IN FERROELECTRIC-ANTIFERROELECTRIC LAYERED CHALCOGENIDES 332 10.5.1 10.5.2 10.5.3 10.5.4 10.6 10.A 10.B LGD-FSM APPROACH 332 PHASE DIAGRAMS OF THE ORDER PARAMETERS 335 BRIGHT AND DARK DOMAIN WALLS 337 COMPARISON WITH EXPERIMENT 339 CONCLUSIONS 341 APPENDIX A: ANALYTICAL EXPRESSIONS FOR THE SOFT PHONON FREQUENCY 342 APPENDIX B: SOFT ACOUSTIC MODE BEHAVIOR IN THE VICINITY OF CRITICAL WAVE VECTORS 345 10.C APPENDIX C: TEMPERATURE DEPENDENCE OF THE STATIC DIELECTRIC SUSCEPTIBILITY 346 10.D APPENDIX D: DERIVATION OF PE-SDFE TRANSITION TEMPERATURE FOR SPHERICAL NANOPARTICLES 347 10.E APPENDIX E: DERIVATION OF PE-PDFE TRANSITION TEMPERATURE FOR SPHERICAL NANOPARTICLES 349 REFERENCES 352 11 APPLICATION EXAMPLES OF FERROELECTRIC 2D LAYERED INDIUM COPPER THIOPHOSPHATE CHALCOGENIDE, CULNP 2 S 6 359 11.1 THE FERROELECTRIC (FE) FAMILY OF METAL (M) HYPO(TIO/SELENO)DIPHOSPHATES 359 CONTENTS IX 11.2 PIEZOELECTRIC AND PYROELECTRIC ACTIVITY AND ELECTROCALORIC EFFECTIVITY OF CUINP 2 S 6 NANOFLAKES 360 11.2.1 11.2.2 11.2.3 11.3 PIEZOACTIVITY OF CUINP 2 S 6 NANOFLAKES 360 PYROACTIVITY OF CUINP 2 S 6 NANOFLAKES 360 ELECTROCALORIC PERFORMANCES OF CUINP 2 S 6 NANOFLAKES 361 PROMISES OF 2D LAYERED CUINP 2 S 6 FOR FERROELECTRIC FIELD EFFECT TRANSISTORS AND MEMORY APPLICATIONS 361 11.3.1 11.3.2 11.3.3 THEORETICAL CONSIDERATIONS AND EVALUATIONS 362 EXPERIMENTAL INVESTIGATIONS AND PROPOSITIONS 362 NEGATIVE CAPACITANCE FIELD EFFECT TRANSISTORS BASED ON TWO-DIMENSIONAL VAN DER WAALS HETEROSTRUCTURES 364 11.4 CONCLUSIONS 365 REFERENCES 366 INDEX 371
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author Banys, Juras
Dziaugys, Andrius
Glukhov, Konstantin E.
Morozovska, Anna Nickolaevna 1977-
Morozovsky, Nicholas V.
Vysochanskii, Yulian M.
author_GND (DE-588)1266517510
(DE-588)1266518347
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author_facet Banys, Juras
Dziaugys, Andrius
Glukhov, Konstantin E.
Morozovska, Anna Nickolaevna 1977-
Morozovsky, Nicholas V.
Vysochanskii, Yulian M.
author_role aut
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physical xii, 381 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm
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spelling Banys, Juras Verfasser (DE-588)1266517510 aut
Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides Juras Banys, Andrius Dziaugys, Konstantin E. Glukhov, Anna N. Morozovska, Nicholas V. Morozovsky, Yulian M. Vysochanskii
Weinheim WILEY-VCH [2022]
xii, 381 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm
txt rdacontent
n rdamedia
nc rdacarrier
Van-der-Waals-Cluster (DE-588)4297539-6 gnd rswk-swf
Phosphorchalkogenide (DE-588)4336418-4 gnd rswk-swf
Ferroelektrikum (DE-588)4154121-2 gnd rswk-swf
Anorganische Chemie
Chemie
Chemistry
Components & Devices
Electrical & Electronics Engineering
Electronic Materials
Elektronische Materialien
Elektrotechnik u. Elektronik
Ferroelektrikum
Festkörperphysik
Inorganic Chemistry
Komponenten u. Bauelemente
Materials Science
Materialwissenschaften
Physics
Physik
Solid State Physics
CH70: Anorganische Chemie
EE60: Komponenten u. Bauelemente
MS40: Elektronische Materialien
PH60: Festkörperphysik
(DE-588)4143413-4 Aufsatzsammlung gnd-content
Phosphorchalkogenide (DE-588)4336418-4 s
Van-der-Waals-Cluster (DE-588)4297539-6 s
Ferroelektrikum (DE-588)4154121-2 s
DE-604
Dziaugys, Andrius Verfasser (DE-588)1266518347 aut
Glukhov, Konstantin E. Verfasser (DE-588)1266519165 aut
Morozovska, Anna Nickolaevna 1977- Verfasser (DE-588)1266042237 aut
Morozovsky, Nicholas V. Verfasser (DE-588)1266519939 aut
Vysochanskii, Yulian M. Verfasser (DE-588)1266520805 aut
Wiley-VCH (DE-588)16179388-5 pbl
Erscheint auch als Online-Ausgabe, PDF 978-3-527-83715-1
Erscheint auch als Online-Ausgabe, EPUB 978-3-527-83716-8
Erscheint auch als Online-Ausgabe 978-3-527-83717-5
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1\p vlb 20220408 DE-101 https://d-nb.info/provenance/plan#vlb
spellingShingle Banys, Juras
Dziaugys, Andrius
Glukhov, Konstantin E.
Morozovska, Anna Nickolaevna 1977-
Morozovsky, Nicholas V.
Vysochanskii, Yulian M.
Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides
Van-der-Waals-Cluster (DE-588)4297539-6 gnd
Phosphorchalkogenide (DE-588)4336418-4 gnd
Ferroelektrikum (DE-588)4154121-2 gnd
subject_GND (DE-588)4297539-6
(DE-588)4336418-4
(DE-588)4154121-2
(DE-588)4143413-4
title Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides
title_auth Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides
title_exact_search Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides
title_exact_search_txtP Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides
title_full Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides Juras Banys, Andrius Dziaugys, Konstantin E. Glukhov, Anna N. Morozovska, Nicholas V. Morozovsky, Yulian M. Vysochanskii
title_fullStr Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides Juras Banys, Andrius Dziaugys, Konstantin E. Glukhov, Anna N. Morozovska, Nicholas V. Morozovsky, Yulian M. Vysochanskii
title_full_unstemmed Van der Waals ferroelectrics properties and device applications of phosphorous chalcogenides Juras Banys, Andrius Dziaugys, Konstantin E. Glukhov, Anna N. Morozovska, Nicholas V. Morozovsky, Yulian M. Vysochanskii
title_short Van der Waals ferroelectrics
title_sort van der waals ferroelectrics properties and device applications of phosphorous chalcogenides
title_sub properties and device applications of phosphorous chalcogenides
topic Van-der-Waals-Cluster (DE-588)4297539-6 gnd
Phosphorchalkogenide (DE-588)4336418-4 gnd
Ferroelektrikum (DE-588)4154121-2 gnd
topic_facet Van-der-Waals-Cluster
Phosphorchalkogenide
Ferroelektrikum
Aufsatzsammlung
url http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35034-6/
http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=033944674&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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