Anion-binding catalysis
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| 008 | 211101s2022 gw a||| |||| 00||| eng d | ||
| 015 | |a 21,N26 |2 dnb | ||
| 016 | 7 | |a 1236033558 |2 DE-101 | |
| 020 | |a 9783527348572 |c hbk. |9 978-3-527-34857-2 | ||
| 020 | |a 3527348573 |9 3-527-34857-3 | ||
| 024 | 3 | |a 9783527348572 | |
| 035 | |a (OCoLC)1298749555 | ||
| 035 | |a (DE-599)DNB1236033558 | ||
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| 084 | |a VK 5580 |0 (DE-625)147406:253 |2 rvk | ||
| 245 | 1 | 0 | |a Anion-binding catalysis |c edited by Olga García Mancheño |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c [2022] | |
| 264 | 4 | |c © 2022 | |
| 300 | |a xvi, 397 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Katalyse |0 (DE-588)4029921-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Aktivierung |g Chemie |0 (DE-588)4141761-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Anion |0 (DE-588)4130938-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Organokatalyse |0 (DE-588)7636906-7 |2 gnd |9 rswk-swf |
| 653 | |a Bioorganic Chemistry | ||
| 653 | |a Bioorganische Chemie | ||
| 653 | |a Catalysis | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Coordination Chemistry | ||
| 653 | |a Katalyse | ||
| 653 | |a Koordinationschemie | ||
| 653 | |a Pharmaceutical & Medicinal Chemistry | ||
| 653 | |a Pharmazeutische u. Medizinische Chemie | ||
| 653 | |a CH40: Katalyse | ||
| 653 | |a CH60: Pharmazeutische u. Medizinische Chemie | ||
| 653 | |a CH72: Koordinationschemie | ||
| 653 | |a CH83: Bioorganische Chemie | ||
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| 689 | 0 | 0 | |a Katalyse |0 (DE-588)4029921-1 |D s |
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| 689 | 0 | 2 | |a Aktivierung |g Chemie |0 (DE-588)4141761-6 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Organokatalyse |0 (DE-588)7636906-7 |D s |
| 689 | 1 | |5 DE-604 | |
| 700 | 1 | |a García Mancheño, Olga |0 (DE-588)1251572537 |4 edt | |
| 710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-83064-0 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-83065-7 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, OBOOK |z 978-3-527-83066-4 |
| 856 | 4 | 2 | |m X:MVB |u http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34857-2/ |3 Kurzbeschreibung |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-032953357 | |
Datensatz im Suchindex
| DE-19_call_number | 1801/VK 5500 G216 |
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| DE-19_location | 85 |
| DE-BY-UBM_katkey | 6264557 |
| DE-BY-UBM_media_number | 41626535930011 |
| _version_ | 1823048870454624256 |
| adam_text | CONTENTS
PREFACE
XI
LIST
OF
ABBREVIATIONS
XIII
1
FROM
ANION
RECOGNITION
TO
ORGANOCATALYTIC
CHEMICAL
REACTIONS
1
FRIEDEMANN
DRESSIER
AND
PETER
R.
SCHREINER
1.1
INTRODUCTION
AND
BACKGROUND
1
1.1.1
EVOLUTION
OF
THIOUREA-BASED
CATALYSTS
10
1.1.2
EVOLUTION
OF
TRIAZOLE-BASED
CATALYSTS
22
1.1.3
PROGRESS
ON
HALOGEN-BINDING-BASED
CATALYSTS
25
1.1.4
MISCELLANEOUS
ANION-BINDING
CATALYSTS
26
1.2
CONCEPTS
IN
ANION-BINDING
CATALYSIS
31
1.2.1
INTRODUCTION
31
1.2.2
ANION-BINDING
CATALYSIS
IN
ADDITION
REACTIONS
36
1.2.3
ANION-BINDING
CATALYSIS
IN
SUBSTITUTION
REACTIONS
44
1.2.4
ANION
BINDING
IN
COOPERATIVE
CATALYSIS
54
1.2.5
ANION-BINDING
IN
LEWIS
ACID
ENHANCEMENT
CATALYSIS
57
1.2.6
ANION-BINDING
IN
PHASE
TRANSFER
CATALYSIS
59
1.3
SUMMARY
AND
OUTLOOK
62
ACKNOWLEDGMENT
63
REFERENCES
64
2
ANION
RECOGNITION
AND
BINDING
CONSTANT
DETERMINATION
79
EDWARD
G.
SHEETZ,
DAVID
VAN
CRAEN,
AND
AMAR
H.
FLOOD
2.1
INTRODUCTION
TO
SUPRAMOLECULAR
CHEMISTRY
AND
BINDING
CONSTANT
DETERMINATION
79
2.1.1
CHAPTER
OVERVIEW
79
2.1.2
SUPRAMOLECULAR
CHEMISTRY
AND
ITS
CONNECTION
TO
ANION-ASSISTED
CATALYSIS
80
2.1.3
BRIEF
HISTORY
OF
ADVANCES
IN
SUPRAMOLECULAR
ANION
BINDING
84
2.1.4
PREDICTING
THE
MODEL
OF
ASSOCIATION
AND
SIMULATING
THE
EXPECTED
SPECIES
DISTRIBUTION
PROFILES
AND
BINDING
CURVES
86
VI
CONTENTS
2.2
EQUILIBRIUM
CONSTANTS,
BINDING
CURVES,
TITRATION
CONDITIONS,
AND
ERRORS
87
2.2.1
PHYSICAL
ORIGINS
OF
EQUILIBRIUM
BINDING
CONSTANTS
87
2.2.2
EXPLANATION
OF
THE
BASIS
FOR
TITRATION
TECHNIQUES
AND
BINDING
CURVES
88
2.2.3
HIROSE
S
RULE
AND
PICKING
THE
RIGHT
CONCENTRATION,
SOLVENT,
AND
TECHNIQUE
89
2.2.4
ERROR
DETERMINATION
92
2.3
EXPERIMENTAL
TECHNIQUES:
NMR
SPECTROSCOPY
92
2.3.1
WHEN
TO
USE
92
2.3.2
SLOW
EXCHANGE
VS.
FAST
EXCHANGE
93
2.3.3
DETERMINATION
OF
THE
UNDERLYING
EQUILIBRIA
94
2.3.4
SOFTWARE
FOR
NON-LINEAR
REGRESSION
FITTING
95
2.3.5
COMMON
ISSUES
97
2.4
EXPERIMENTAL
TECHNIQUES:
UV-VIS
SPECTROSCOPY
97
2.4.1
WHEN
TO
USE
97
2.4.2
PHYSICAL
ORIGINS
OF
OPTICAL
PHENOMENA
97
2.4.3
SOFTWARE
FOR
NON-LINEAR
REGRESSION
ANALYSIS
OF
UV-VIS
TITRATIONS
98
2.4.4
COMMON
ISSUES
99
2.5
UNDERAPPRECIATED
CONCERNS
IN
BINDING
CONSTANT
DETERMINATION:
MULTIPLE
BINDING
EQUILIBRIA
99
2.5.1
WHEN
TO
EXPECT
ADDITIONAL
EQUILIBRIA
99
2.5.2
HOW
TO
DIAGNOSE
ADDITIONAL
EQUILIBRIA
100
2.5.3
HOW
TO
ACCOUNT
FOR
ADDITIONAL
EQUILIBRIA
101
2.6
UNDERAPPRECIATED
CONCERNS
IN
BINDING
CONSTANT
DETERMINATION:
ION
PAIRING
102
2.6.1
WHEN
TO
EXPECT
ION
PAIRING
102
2.6.2
ROLE
OF
SOLVENT
AND
CONCENTRATION
IN
ION
PAIRING
103
2.6.3
HOW
TO
DIAGNOSE
ION
PAIRING
103
2.7
UNDERAPPRECIATED
CONCERNS
IN
BINDING
CONSTANT
DETERMINATION:
KINETIC
PROCESSES
104
2.8
CONNECTING
EQUILIBRIUM
CONSTANTS
TO
STRUCTURES
AND
CATALYSIS
104
2.9
CONCLUSION
105
ACKNOWLEDGMENT
105
REFERENCES
105
3
(THIO)UREA
AND
SQUARAMIDE-CATALYZED
ANION-BINDING
CATALYSIS
WITH
HALOGEN
ANIONS
111
MATTHEW
A.
HORWITZ
AND
VERONIQUE
GOUVERNEUR
3.1
INTRODUCTION
111
3.2
HISTORY
AND
BACKGROUND
111
3.3
ASYMMETRIC
CATALYSIS
BY
CATALYST
ASSOCIATION
WITH
THE
ELECTROPHILE
113
3.3.1
EXAMPLES
UTILIZING
THE
N-ACYLIMINIUM
CHLORIDE
ION
PAIR
113
3.3.1.1
PICTET-SPENGLER
REACTION
AND
VARIANTS
113
CONTENTS
VII
3.3.1.2
INTRAMOLECULAR
CYCLIZATIONS
WITH
OTHER
(HETERO)AROMATIC
NUCLEOPHILES
115
3.3.1.3
INTRAMOLECULAR
AND
INTERMOLECULAR
AZA-SAKURAI
REACTION
116
3.3.1.4
MANNICH
REACTION
AND
VARIANTS
120
3.3.1.5
PETASIS-TYPE
REACTIONS
121
3.3.2
EXAMPLES
UTILIZING
ELECTROPHILES
OTHER
THAN
N-ACYLIMINIUM
ION
PRECURSORS
123
3.3.2.1
UTILIZATION
OF
OXOCARBENIUM
AND
PYRONE
INTERMEDIATES
123
3.3.2.2
GLYCOSYLATION
REACTIONS
UTILIZING
HBD-HALIDE
BINDING
126
3.3.2.3
UTILIZATION
OF
NON-HETEROATOM-STABILIZED
CARBOCATIONS
AS
ELECTROPHILES
127
3.4
ASYMMETRIC
CATALYSIS
BY
CATALYST
ASSOCIATION
WITH
THE
NUCLEOPHILE
129
3.4.1
CATALYST-NUCLEOPHILE
ASSOCIATION
IN
PHASE-TRANSFER
CATALYSIS
130
3.4.1.1
INVESTIGATION
OF
HYDROGEN-BONDED
FLUORIDE:
STRUCTURE
AND
REACTIVITY
130
3.4.1.2
DEVELOPMENT
OF
HYDROGEN-BONDING
PHASE-TRANSFER
CATALYSIS
(HBPTC)
130
3.4.1.3
DEVELOPMENT
OF
ACYL-TRANSFER
CATALYSIS
WITH
HYDROGEN-BONDED
FLUORIDE
134
3.4.2
CATALYST-NUCLEOPHILE
ASSOCIATION
IN
HOMOGENEOUS
CATALYSIS
135
3.5
CONCLUSIONS
AND
OUTLOOK
136
ACKNOWLEDGMENTS
137
REFERENCES
137
4
CHIRAL
UREAS,
THIOUREAS,
AND
SQUARAMIDES
IN
ANION-BINDING
CATALYSIS
WITH
CO-CATALYTIC
BRONSTED/LEWIS
ACIDS
141
ADAM
TROTTA
AND
ERIC
N.
LACOBSEN
4.1
INTRODUCTION
141
4.2
CARBOXYLIC
ACID
CO-CATALYSTS
141
4.3
SULFONIC
ACID
CO-CATALYSTS
148
4.4
MINERAL
ACID
CO-CATALYSTS
152
4.5
LEWIS
ACID
CO-CATALYSTS
155
4.6
CONCLUSIONS
AND
OUTLOOK
157
REFERENCES
157
5
ANION-BINDING
CATALYSIS
WITH
OTHER
ANIONS
161
SANKASH
MITRA
AND
SANTANU
MUKHERJEE
5.1
INTRODUCTION
161
5.2
CYANIDE
ANION
162
5.2.1
STRECKER
REACTION
163
5.2.2
ACYLCYANATION
OF
IMINES
168
5.3
OXYGEN-BASED
ANIONS
169
5.3.1
ALKOXIDES
AND
ENOLATES
169
5.3.2
ENOLATES
OF
LACTONES,
CYCLIC
ANHYDRIDES,
AND
IMIDES
174
5.3.3
CARBOXYLATES
182
VIII
I
CONTENTS
5.4
CONCLUSIONS
AND
OUTLOOK
192
REFERENCES
193
6
SILANEDIOLS,
PHOSPHORAMIDES,
AND
OTHER
OH
AND
NH-BASED
H-DONOR
CATALYSTS
207
ALEXANDRIA
LEVEILLE
AND
ANITA
MATTSON
6.1
INTRODUCTION
201
6.2
SILANEDIOLS
201
6.2.1
INTRODUCTION
207
6.2.2
OVERVIEW
OF
SILANOLS
IN
ANION
BINDING
AND
CATALYSIS
202
6.2.3
SILANEDIOL
ANION-BINDING
CATALYSIS
203
6.2.4
ALKOXYSILANEDIOL
ANION
BINDING
CATALYSIS
207
6.3
SILOXANES
208
6.4
THIOPHOSPHORAMIDES
270
6.5
CYCLODIPHOSPHAZANES
213
6.6
OTHER
EXAMPLES
275
6.6.1
XANTHENE-DIAMINE
SCAFFOLD
275
6.6.2
CROCONAMIDES
276
6.6.3
PYRROLE-BASED
ANION-BINDING
CATALYST
277
6.6.4
BISAMIDINE
CATALYSTS
277
6.7
CONCLUSIONS
218
REFERENCES
218
1
1,2,3-TRIAZOLES
AND
1,2,3-TRIAZOLIUM
IONS
AS
CATALYSTS
227
KOHSUKE
OHMATSU
AND
TAKASHI
OOI
7.1
INTRODUCTION
221
7.2
TRIAZOLE-BASED
ANION-BINDING
MOLECULAR
CATALYSTS
224
7.3
TRIAZOLIUM
IONS
AS
ORGANIC
MOLECULAR
CATALYSTS
WITH
ANION-BINDING
ABILITY
231
7
A
TRIAZOLIUM
IONS
IN
DUAL
FUNCTIONAL
CATALYSTS
240
7.5
CONCLUSION
241
REFERENCES
242
8
QUATERNARY
AMMONIUM,
PHOSPHONIUM,
AND
TERTIARY
SULFONIUM
SALTS
AS
HYDROGEN-BONDING
CATALYSTS
249
SEIJI
SHIRAKAWA
8.1
INTRODUCTION
249
8.2
HYDROGEN-BONDING
ABILITY
OF
QUATERNARY
AMMONIUM
SALTS
249
8.3
HYDROGEN-BONDING
CATALYSIS
OF
QUATERNARY
AMMONIUM
SALTS
257
8.4
HYDROGEN-BONDING
CATALYSIS
OF
QUATERNARY
PHOSPHONIUM
SALTS
257
8.5
HYDROGEN-BONDING
CATALYSIS
OF
TERTIARY
SULFONIUM
SALTS
260
8.6
CONCLUSION
264
REFERENCES
264
CONTENTS
IX
9
ASSISTED
AND
DUAL
ANION
BINDING
IN
AMINO
AND
NUCLEOPHILIC
CATALYSIS
271
EFRAIM
REYES,
QUI-NHI
DUONG,
LIHER
PRIETO,
OLGA
GARCIA
MANCHENO,
AND
JOSE
L.
VICARIO
9.1
DUAL
AMINO/H-BOND
DONOR
CATALYSIS
271
9.1.1
ENAMINE
ACTIVATION
272
9.1.2
DIENAMINE
ACTIVATION
276
9.1.3
IMINIUM
ION
ACTIVATION
278
9.1.4
VINYLOGOUS
IMINIUM
ION
ACTIVATION
283
9.2
THIOUREA
-
PYRIDINE-BASED
NUCLEOPHILIC
DUAL
CATALYSIS
284
9.2.1
KINETIC
RESOLUTION
AND
DESYMMETRIZATION
OF
AMINES
284
9.2.2
ASYMMETRIC
STEGLICH
REARRANGEMENT
290
9.2.3
OTHER
ACYLATION
REACTIONS
296
9.2.4
ANION-BINDING-ASSISTED
POLYMERIZATION
REACTIONS
296
9.3
CONCLUSIONS
298
REFERENCES
299
10
ANION-BINDING
CATALYSIS
BY
HALOGEN,
CHALCOGEN,
PNICTOGEN,
AND
TETREL
BONDING
307
RAFFAELLA
PAPAGNA,
LUKAS
VOGEL,
AND
STEFAN
M.
HUBER
10.1
HISTORY
OF
HALOGEN
BONDING
307
10.2
HISTORY
OF
CHALCOGEN
BONDING
310
10.3
HISTORY
OF
PNICTOGEN
AND
TETREL
BONDING
314
10.4
DIFFERENCES
BETWEEN
HYDROGEN
BONDING
AND
OTHER
SECONDARY
INTERACTIONS
315
10.5
SECONDARY
BONDING
IN
ANION
RECOGNITION
316
10.6
HALOGEN
BONDING
IN
ANION-BINDING
CATALYSIS
322
10.7
CHALCOGEN
BONDING
IN
ANION-BINDING
CATALYSIS
328
10.8
PNICTOGEN
AND
TETREL
BONDING
IN
ANION-BINDING
CATALYSIS
331
10.9
CONCLUSION
333
REFERENCES
334
11
NEW
TRENDS
AND
SUPRAMOLECULAR
APPROACHES
IN
ANION-BINDING
CATALYSIS
345
MARIA
C.
PEREZ-AGUILAR,
MELANIA
GOMEZ-MARTINEZ,
JAN
KUHLMANN,
AND
OLGA
GARCIA
MANCHENO
11.1
GENERAL
INTRODUCTION
345
11.2
DUAL
PHOTOREDOX
AND
ANION-BINDING
CATALYSIS
345
11.3
COMBINATION
OF
METAL
AND
ANION-BINDING
CATALYSIS
351
11.3.1
ANION-BINDING
ASSISTED
HYDROGENATION
REACTIONS
351
11.3.2
HYDROFORMYLATION
REACTIONS
355
11.3.3
ANION-BINDING
-
METAL-CATALYZED
C-C
FORMING
REACTIONS
358
11.4
SUPRAMOLECULAR
APPROACHES
INVOLVING
ANION-BINDING
CATALYSIS
359
X
CONTENTS
11.4.1
MECHANICALLY
INTERLOCKED
MOLECULES
IN
ANION-BINDING
CATALYSIS
359
11.4.1.1
MOLECULAR
KNOTS
AS
ANION-BINDING
CATALYSTS
360
11.4.1.2
ROTAXANES
AS
ANION-BINDING
CATALYSTS
363
11.4.2
MOLECULAR
MOTORS
IN
ANION-BINDING
CATALYSIS
364
11.4.3
MACROCYCLES
IN
ANION-BINDING
CATALYSIS
365
11.5
ANION-JT
CATALYSIS
368
11.5.1
ANION-%-CATALYZED
KEMP
ELIMINATION
REACTION
369
11.5.2
ANION-IT
INTERACTIONS
IN
ENOLATE
CHEMISTRY
370
11.5.3
EPOXIDE-OPENING
-
ETHER
CYCLIZATION
REACTIONS
372
11.5.4
ENANTIOSELECTIVE
ANION-::
CATALYSIS
373
11.5.5
MISCELLANEOUS
376
11.6
CONCLUSION
AND
OUTLOOK
376
REFERENCES
377
INDEX
387
|
| any_adam_object | 1 |
| author2 | García Mancheño, Olga |
| author2_role | edt |
| author2_variant | m o g mo mog |
| author_GND | (DE-588)1251572537 |
| author_facet | García Mancheño, Olga |
| building | Verbundindex |
| bvnumber | BV047567674 |
| classification_rvk | VK 5550 VK 5580 |
| ctrlnum | (OCoLC)1298749555 (DE-599)DNB1236033558 |
| discipline | Chemie / Pharmazie |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV047567674 |
| illustrated | Illustrated |
| indexdate | 2025-02-03T15:58:23Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527348572 3527348573 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032953357 |
| oclc_num | 1298749555 |
| open_access_boolean | |
| owner | DE-11 DE-19 DE-BY-UBM DE-703 |
| owner_facet | DE-11 DE-19 DE-BY-UBM DE-703 |
| physical | xvi, 397 Seiten Illustrationen, Diagramme |
| publishDate | 2022 |
| publishDateSearch | 2022 |
| publishDateSort | 2022 |
| publisher | Wiley-VCH |
| record_format | marc |
| spellingShingle | Anion-binding catalysis Katalyse (DE-588)4029921-1 gnd Aktivierung Chemie (DE-588)4141761-6 gnd Anion (DE-588)4130938-8 gnd Organokatalyse (DE-588)7636906-7 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4141761-6 (DE-588)4130938-8 (DE-588)7636906-7 (DE-588)4143413-4 |
| title | Anion-binding catalysis |
| title_auth | Anion-binding catalysis |
| title_exact_search | Anion-binding catalysis |
| title_full | Anion-binding catalysis edited by Olga García Mancheño |
| title_fullStr | Anion-binding catalysis edited by Olga García Mancheño |
| title_full_unstemmed | Anion-binding catalysis edited by Olga García Mancheño |
| title_short | Anion-binding catalysis |
| title_sort | anion binding catalysis |
| topic | Katalyse (DE-588)4029921-1 gnd Aktivierung Chemie (DE-588)4141761-6 gnd Anion (DE-588)4130938-8 gnd Organokatalyse (DE-588)7636906-7 gnd |
| topic_facet | Katalyse Aktivierung Chemie Anion Organokatalyse Aufsatzsammlung |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34857-2/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032953357&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT garciamanchenoolga anionbindingcatalysis AT wileyvch anionbindingcatalysis |