Industrial separation processes fundamentals

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Hauptverfasser: Haan, André B. de 1964- (VerfasserIn), Eral, H. Burak (VerfasserIn), Schuur, Boelo 1978- (VerfasserIn)
Format: Buch
Sprache:English
Veröffentlicht: Berlin De Gruyter [2020]
Ausgabe:2nd edition
Schriftenreihe:De Gruyter graduate
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Datensatz im Suchindex

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adam_text CONTENTS PREFACE * V CHAPTER 1 CHARACTERISTICS OF SEPARATION PROCESSES * 1 1.1 1.2 1.2.1 1.2.2 1.2.3 1.3 1.3.1 1.3.2 1.4 1.4.1 1.4.2 SIGNIFICANCE OF SEPARATIONS * 1 CHARACTERISTICS OF SEPARATION PROCESSES * 4 CATEGORIZATION * 4 SEPARATING AGENTS * 5 SEPARATION FACTORS * 7 INDUSTRIAL SEPARATION METHODS * 8 EXPLOITABLE PROPERTIES * 8 IMPORTANT MOLECULAR SEPARATIONS * 10 INHERENT SELECTIVITY * 11 EQUILIBRIUM-BASED PROCESSES * 11 RATE-CONTROLLED PROCESSES * 13 NOMENCLATURE * 14 EXERCISES * 14 CHAPTER 2 EVAPORATION AND DISTILLATION * 17 2.1 2.1.1 2.1.2 2.2 2.2.1 2.2.2 2.2.2.1 2.2.2.2 2.3 2.3.1 2.3.2 2.3.3 2.3.4 2.4 2.4.1 2.4.1.1 2.4.1.2 2.4.1.3 2.4.1.4 2.4.2 SEPARATION BY EVAPORATION * 17 INTRODUCTION * 17 VAPOR-LIQUID EQUILIBRIA * 18 SEPARATION BY SINGLE-STAGE PARTIAL EVAPORATION * 23 DIFFERENTIAL DISTILLATION * 23 FLASH DISTILLATION * 24 SPECIFYING T AND L/V ----- 26 SPECIFYING T AND P TOT -----26 MULTISTAGE DISTILLATION * 28 DISTILLATION CASCADES * 28 COLUMN DISTILLATION * 29 FEASIBLE DISTILLATION CONDITIONS * 31 EXTERNAL COLUMN BALANCES * 31 MCCABE-THIELE ANALYSIS * 32 INTERNAL BALANCES * 32 RECTIFYING SECTION * 33 STRIPPING SECTION * 34 FEED STAGE CONSIDERATIONS * 35 FEED LINE * 36 REQUIRED NUMBER OF EQUILIBRIUM STAGES * 37 VIII CONTENTS 2.4.2.1 2.4.2.2 2.4.23 2.4.2.4 2.4.3 2.5 2.5.1 2.5.2 2.5.3 GRAPHICAL DETERMINATION OF STAGES AND LOCATION OF FEED STAGE ----- 37 LIMITING CONDITIONS ----- 40 FENSKE AND UNDERWOOD EQUATIONS * 41 USE OF MURPHREE EFFICIENCY ----- 44 ENERGY REQUIREMENTS * 45 ADVANCED DISTILLATION TECHNIQUES * 45 BATCH DISTILLATION ----- 45 CONTINUOUS SEPARATION OF MULTIPLE PRODUCT MIXTURES * 47 SEPARATION OF AZEOTROPES * 48 NOMENCLATURE * 50 EXERCISES ----- 51 CHAPTER 3 ABSORPTION AND STRIPPING * 57 3.1 3.2 3.3 3.4 3.4.1 3.4.2 3.5 3.5.1 3.5.2 3.5.3 3.6 3.6.1 3.6.2 3.6.3 3.6.4 INTRODUCTION * 57 THE AIM OF ABSORPTION * 59 GENERAL DESIGN APPROACH * 60 ABSORPTION AND STRIPPING EQUILIBRIA * 61 GASEOUS SOLUTE SOLUBILITIES * 61 MINIMUM ABSORBENT FLOW * 63 ABSORBER AND STRIPPER DESIGN * 64 OPERATING LINES FOR ABSORPTION * 64 STRIPPING ANALYSIS * 68 ANALYTICAL KREMSER SOLUTION * 69 INDUSTRIAL ABSORBERS * 72 PACKED COLUMNS * 73 PLATE COLUMNS * 74 SPRAY AND BUBBLE COLUMNS * 74 COMPARISON OF ABSORPTION COLUMNS * 75 NOMENCLATURE * 77 EXERCISES ----- 77 CHAPTER 4 GENERAL DESIGN OF GAS/LIQUID CONTACTORS * 81 4.1 4.2 4.3 4.3.1 4.3.2 4.3.2.1 43.2.2 4.3.23 INTRODUCTION * 81 MODELING MASS TRANSFER * 81 PLATE COLUMNS * 86 DIMENSIONING A TRAY COLUMN * 89 HEIGHT OF A TRAY COLUMN * 90 TRAY SPACING * 90 TRAY EFFICIENCY * 90 TRANSFER UNITS * 92 CONTENTS * IX 4.3.2.4 OVERALL EFFICIENCY ----- 93 4.3.3 DIAMETER OF A TRAY COLUMN * 95 4.3.3.1 FLOODING ----- 96 4.3.3.2 DOWNCOMER FLOODING ----- 97 4.33.3 ENTRAINMENT FLOODING * 99 4.33.4 TRAY DIAMETER AND PRESSURE DROP * 100 4.33.5 REMARK ON FLOODING CHARTS * 100 4.4 PACKED COLUMNS ----- 101 4.4.1 RANDOM PACKING * 102 4.4.2 STRUCTURED PACKING ----- 103 4.4.3 DIMENSIONING A PACKED COLUMN * 104 4.4.4 HEIGHT OF A PACKED COLUMN * 105 4.4.4.1 TRANSFER UNITS ------ 105 4.4.5 MINIMUM COLUMN DIAMETER ----- 108 4.4.6 PRESSURE DROP ----- 110 4.5 CRITERIA FOR COLUMN SELECTION * 111 NOMENCLATURE * 112 EXERCISES * 113 CHAPTER 5 LIQUID-LIQUID EXTRACTION * 117 5.1 INTRODUCTION * 117 5.1.1 GENERAL INTRODUCTION * 117 5.1.2 LIQUID-LIQUID EQUILIBRIA * 120 5.1.3 SOLVENT SELECTION * 121 5.2 EXTRACTION SCHEMES * 123 5.2.1 SINGLE EQUILIBRIUM STAGE * 124 5.2.2 COCURRENT CASCADE * 125 5.2.3 CROSSCURRENT * 126 5.2.4 COUNTERCURRENT * 126 5.3 DESIGN OF COUNTERCURRENT EXTRACTIONS * 127 5.3.1 GRAPHICAL MCCABE-THIELE METHOD FOR IMMISCIBLE SYSTEMS * 127 5.3.2 ANALYTICAL KREMSER METHOD FOR IMMISCIBLE SYSTEMS * 130 5.3.3 GRAPHICAL METHOD FOR PARTIALLY MISCIBLE SYSTEMS * 131 5.3.4 EFFICIENCY OF AN IDEAL NONEQUILIBRIUM MIXER * 136 5.4 INDUSTRIAL LIQUID-LIQUID EXTRACTORS * 137 5.4.1 MIXER-SETTLERS * 137 5.4.2 MECHANICALLY AGITATED COLUMNS * 138 5.4.3 UNAGITATED AND PULSED COLUMNS * 139 5.4.4 CENTRIFUGAL EXTRACTORS * 141 X CONTENTS 5.4.5 SELECTION OF AN EXTRACTOR * 143 NOMENCLATURE * 147 EXERCISES * 147 CHAPTER 6 ADSORPTION AND ION EXCHANGE * 155 6.1 INTRODUCTION * 155 6.2 ADSORPTION FUNDAMENTALS * 158 6.2.1 INDUSTRIAL ADSORBENTS * 158 6.2.2 EQUILIBRIA ----- 164 6.2.3 KINETICS ----- 168 6.3 FIXED-BED ADSORPTION * 171 6.3.1 BED PROFILES AND BREAKTHROUGH CURVES * 171 6.3.2 EQUILIBRIUM THEORY MODEL * 173 6.3.3 MODELING OF MASS TRANSFER EFFECTS * 175 6.4 BASIC ADSORPTION/DESORPTION CYCLES * 177 6.4.1 TEMPERATURE SWING * 179 6.4.2 PRESSURE SWING * 180 6.4.3 INERT AND DISPLACEMENT PURGE CYCLES * 181 6.5 PRINCIPLES OF ION EXCHANGE * 182 6.5.1 ION EXCHANGE RESINS * 183 6.5.2 EQUILIBRIA AND SELECTIVITY * 184 6.6 ION EXCHANGE PROCESSES * 185 NOMENCLATURE * 187 EXERCISES * 188 CHAPTER 7 DRYING OF SOLIDS * 195 7.1 INTRODUCTION ----- 195 7.2 HUMIDITY OF CARRIER GAS * 196 7.2.1 DEFINITIONS * 196 7.2.2 AIR-WATER SYSTEM: A SPECIAL CASE * 198 7.2.3 PSYCHROMETRIC CHARTS * 199 7.3 MOISTURE IN SOLIDS * 201 7.3.1 BOUND AND UNBOUND WATER * 201 7.4 DRYING MECHANISMS ----- 206 7.4.1 CONSTANT DRYING RATE * 207 7.4.2 FALLING DRYING RATE ----- 208 7.4.3 ESTIMATION OF DRYING TIME ----- 208 7.5 CLASSIFICATION OF DRYING OPERATIONS * 210 7.5.1 DIRECT-HEAT DRYERS * 211 7.5.1.1 BATCH COMPARTMENT DRYERS * 212 CONTENTS * XI 7.5.1.2 BELT DRYERS * 212 7.5.1.3 ROTARY DRYERS ----- 213 7.5.1.4 FLASH DRYERS ----- 214 7.5.1.5 FLUIDIZED BED DRYERS * 214 7.5.1.6 SPRAY DRYERS * 216 7.5.2 CONTACT DRYERS * 217 7.5.2.1 ROTARY AND AGITATOR DRYERS ------ 217 7.5.2.2 VACUUM DRYERS * 217 7.5.2.3 FLUID BED DRYERS ------ 218 7.5.3 OTHER DRYING METHODS * 219 NOMENCLATURE ----- 220 EXERCISES * 221 APPENDIX ----- 223 CHAPTER 8 CRYSTALLIZATION * 227 8.1 INTRODUCTION ----- 227 8.2 CRYSTAL QUALITY PARAMETERS * 232 8.2.1 CRYSTAL SIZE DISTRIBUTION * 233 8.2.2 MORPHOLOGY ----- 234 8.2.3 CRYSTAL FORM ----- 235 8.2.4 PURITY ----- 236 8.2.5 INTERDEPENDENCY AMONG CRYSTAL QUALITY PARAMETERS * 237 8.3 PHASE DIAGRAMS * 237 8.3.1 PREDICTING SOLUBILITY CURVES * 241 8.3.2 MEASURING SOLUBILITY CURVES * 241 8.4 KINETICS OF CRYSTALLIZATION * 242 8.4.1 METASTABLE ZONE LIMIT * 242 8.4.2 MEASURING METASTABLE ZONE WIDTH * 244 8.4.3 SUPERSATURATION * 244 8.4.4 THEORY OF CRYSTALLIZATION * 245 8.4.5 NUCLEATION * 247 8.4.6 CRYSTAL GROWTH ----- 252 8.4.7 POPULATION BALANCE EQUATIONS FOR THE MSMPR CRYSTALLIZER * 255 8.5 METHODS OF SUPERSATURATION GENERATION * 259 8.5.1 COOLING ----- 259 8.5.2 EVAPORATION * 260 8.5.3 VACUUM CRYSTALLIZATION * 260 8.5.4 PRECIPITATION * 261 8.5.5 ANTI-SOLVENT CRYSTALLIZATION ----- 262 8.5.6 MELT CRYSTALLIZATION ----- 263 XII CONTENTS 8.5.7 CHOOSING A METHOD OF SUPERSATURATION GENERATION * 263 8.6 BASIC DESIGN FOR INDUSTRIAL CRYSTALLIZERS * 264 8.6.1 PROCESS AND DESIGN SPECIFICATIONS * 266 8.6.2 THERMODYNAMIC AND LAB-SCALE KINETIC INFORMATION * 266 8.6.3 DESIGN DECISIONS * 267 8.6.3.1 SELECTING METHOD OF SUPERSATURATION GENERATION * 267 8.63.2 OPERATION MODES: BATCH VERSUS CONTINUOUS OPERATION * 268 8.6.3.3 NUMBER OF STAGES: SINGLE- AND MULTISTAGE OPERATION SELECTION * 270 8.63.4 SELECTING THE CRYSTALLIZER TYPE * 270 8.63.5 STIRRED TANK AND COOLING DISK CRYSTALLIZER * 271 8.63.6 FORCED CIRCULATION CRYSTALLIZERS * 272 8.63.7 DRAFT TUBE BAFFLE CRYSTALLIZER * 273 8.63.8 FLUIDIZED BED CRYSTALLIZERS * 273 8.63.9 MELT CRYSTALLIZERS * 274 8.6.3.10 VACUUM CRYSTALLIZERS * 276 8.7 CRYSTALLIZER CALCULATIONS * 277 8.7.1 MASS BALANCE * 277 8.7.2 BASIC YIELD CALCULATIONS * 278 8.7.3 ENTHALPY BALANCE * 279 8.7.4 CRYSTALLIZER DIMENSIONS * 280 8.8 FINAL DESIGN PROCEDURE * 281 8.8.1 ECONOMIC EVALUATION * 281 8.8.2 DETAILED DESIGN WITH PRODUCTION SCALE KINETIC DATA * 282 NOMENCLATURE * 283 EXERCISES * 284 CHAPTER 9 SEDIMENTATION AND SETTLING * 289 9.1 INTRODUCTION * 289 9.2 GRAVITY SEDIMENTATION * 290 9.2.1 SEDIMENTATION MECHANISMS * 291 9.2.2 DILUTE SEDIMENTATION * 293 9.2.3 HINDERED SETTLING * 296 9.2.4 CONTINUOUS SEDIMENTATION TANK (GRAVITY-SETTLING TANK) * 296 9.2.5 GRAVITY SEDIMENTATION EQUIPMENT * 299 9.2.6 BROWNIAN MOTION AND ITS INFLUENCE ON SEDIMENTATION * 300 9.2.7 COLLOIDAL STABILITY * 302 9.3 CENTRIFUGAL SEDIMENTATION * 303 9.3.1 PARTICLE VELOCITY IN A CENTRIFUGAL FIELD * 304 9.3.2 SEDIMENTING CENTRIFUGES * 304 9.3.3 BOWL CENTRIFUGE SEPARATION CAPABILITY * 307 CONTENTS * XIII 9.3.4 9.3.5 9.3.6 9.4 9.4.1 9.4.2 THE SIGMA CONCEPT * 308 CAPACITY OF DISK CENTRIFUGES * 310 HYDROCYCLONES ----- 311 ELECTROSTATIC PRECIPITATION * 315 PRINCIPLES * 315 EQUIPMENT AND COLLECTING EFFICIENCY * 317 NOMENCLATURE * 319 EXERCISES * 320 CHAPTER 10 FILTRATION * 325 10.1 10.2 10.2.1 10.2.2 10.2.3 10.2.4 10.3 10.3.1 10.3.2 10.3.3 10.4 10.5 10.5.1 10.5.2 10.6 10.6.1 10.6.2 10.6.3 10.6.4 THE FILTRATION PROCESS * 325 FILTRATION FUNDAMENTALS * 328 FLOW THROUGH PACKED BEDS * 328 CAKE FILTRATION * 329 CONSTANT PRESSURE AND CONSTANT RATE FILTRATION * 331 COMPRESSIBLE CAKES * 332 FILTRATION EQUIPMENT * 333 CONTINUOUS LARGE-SCALE VACUUM FILTERS * 334 BATCH VACUUM FILTERS * 337 PRESSURE FILTERS * 338 FILTER MEDIA * 340 CENTRIFUGAL FILTRATION * 342 CENTRIFUGAL FILTERS * 342 FILTRATION RATES IN CENTRIFUGES * 344 INTERCEPTIVE FILTRATION * 347 DEEP BED FILTRATION * 347 IMPINGEMENT FILTRATION OF GASES * 348 INTERCEPTION MECHANISMS * 350 LAMELLAR PLATE SEPARATORS * 352 NOMENCLATURE * 353 EXCERCISES * 353 CHAPTER 11 MEMBRANE FILTRATION * 359 11.1 11.2 11.3 11.4 11.4.1 11.4.2 INTRODUCTION * 359 MEMBRANE SELECTION * 360 MEMBRANE FILTRATION PROCESSES * 362 FLUX EQUATIONS AND SELECTIVITY * 365 FLUX DEFINITIONS * 366 PERMEABILITY FOR DIFFUSION IN POROUS MEMBRANES * 367 XIV * CONTENTS 11.4.3 11.4.4 11.5 11.6 11.6.1 11.7 PERMEABILITY FOR SOLUTION-DIFFUSION IN DENSE MEMBRANES * 369 SELECTIVITY AND RETENTION ----- 370 CONCENTRATION POLARIZATION * 372 MEMBRANE MODULES ----- 375 DESIGN PROCEDURE * 379 CONCLUDING REMARKS * 380 NOMENCLATURE ----- 381 EXERCISES ----- 382 APPENDIX ----- 384 CHAPTER 12 SEPARATION METHOD SELECTION * 385 12.1 INTRODUCTION * 385 12.1.1 INDUSTRIAL SEPARATION PROCESSES * 385 12.1.2 FACTORS INFLUENCING THE CHOICE OF A SEPARATION PROCESS * 387 12.1.2.1 ECONOMICS ----- 387 12.1.2.2 FEASIBILITY ----- 388 12.1.2.3 PRODUCT STABILITY ----- 389 12.1.2.4 DESIGN RELIABILITY * 389 12.2 SELECTION OF FEASIBLE SEPARATION PROCESSES * 390 12.2.1 CLASSES OF PROCESSES * 390 12.2.2 INITIAL SCREENING * 391 12.2.3 SEPARATION FACTOR * 392 12.3 SEPARATION OF HOMOGENEOUS LIQUID MIXTURES * 394 12.3.1 STRENGTHS OF DISTILLATION * 394 12.3.2 LIMITATIONS OF DISTILLATION * 397 12.3.3 LOW RELATIVE VOLATILITIES * 399 12.3.4 OVERLAPPING BOILING POINTS * 401 12.3.5 LOW CONCENTRATIONS * 402 12.3.6 DISSOLVED SOLIDS * 403 12.4 SEPARATOR, SYSTEMS FOR GAS MIXTURES * 404 12.4.1 GENERAL SELECTION CONSIDERATIONS * 404 12.4.2 COMPARISON OF GAS SEPARATION TECHNIQUES * 406 12.4.2.1 ABSORPTION * 406 12.4.2.2 ADSORPTION * 407 12.4.2.3 MEMBRANE SEPARATION * 407 12.5 SEPARATION METHODS FOR SOLID-LIQUID MIXTURES * 408 EXCERCISES * 410 APPENDIX ANSWERS TO EXERCISES * 413 REFERENCES AND FURTHER READING * 425 INDEX * 429 CONTENTS * XV
any_adam_object 1
author Haan, André B. de 1964-
Eral, H. Burak
Schuur, Boelo 1978-
author_GND (DE-588)1036241904
(DE-588)1215048742
(DE-588)1215047959
author_facet Haan, André B. de 1964-
Eral, H. Burak
Schuur, Boelo 1978-
author_role aut
aut
aut
author_sort Haan, André B. de 1964-
author_variant a b d h abd abdh
h b e hb hbe
b s bs
building Verbundindex
bvnumber BV046854315
classification_rvk VN 7180
VN 7121
VN 7120
ctrlnum (OCoLC)1190728635
(DE-599)DNB1199023809
discipline Chemie / Pharmazie
edition 2nd edition
format Book
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isbn 9783110654738
3110654733
language English
oai_aleph_id oai:aleph.bib-bvb.de:BVB01-032263084
oclc_num 1190728635
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DE-11
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physical XV, 439 Seiten Illustrationen, Diagramme
publishDate 2020
publishDateSearch 2020
publishDateSort 2020
publisher De Gruyter
record_format marc
series2 De Gruyter graduate
spellingShingle Haan, André B. de 1964-
Eral, H. Burak
Schuur, Boelo 1978-
Industrial separation processes fundamentals
Trennverfahren (DE-588)4078395-9 gnd
subject_GND (DE-588)4078395-9
title Industrial separation processes fundamentals
title_auth Industrial separation processes fundamentals
title_exact_search Industrial separation processes fundamentals
title_full Industrial separation processes fundamentals André B. de Haan, H. Burak Eral, Boelo Schuur
title_fullStr Industrial separation processes fundamentals André B. de Haan, H. Burak Eral, Boelo Schuur
title_full_unstemmed Industrial separation processes fundamentals André B. de Haan, H. Burak Eral, Boelo Schuur
title_short Industrial separation processes
title_sort industrial separation processes fundamentals
title_sub fundamentals
topic Trennverfahren (DE-588)4078395-9 gnd
topic_facet Trennverfahren
url http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110654738&searchTitles=true
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