Selenium and tellurium reagents in chemistry and materials science
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De Gruyter
[2019]
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| 007 | t| | ||
| 008 | 190114s2019 gw a||| |||| 00||| eng d | ||
| 015 | |a 18,N04 |2 dnb | ||
| 016 | 7 | |a 1150716096 |2 DE-101 | |
| 020 | |a 9783110527940 |c hbk. |9 978-3-11-052794-0 | ||
| 020 | |a 3110527944 |9 3-11-052794-4 | ||
| 035 | |a (OCoLC)1091669099 | ||
| 035 | |a (DE-599)DNB1150716096 | ||
| 040 | |a DE-604 |b ger |e rda | ||
| 041 | 0 | |a eng | |
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| 049 | |a DE-29T |a DE-19 |a DE-11 | ||
| 084 | |a VK 7716 |0 (DE-625)147438: |2 rvk | ||
| 084 | |a VK 7717 |0 (DE-625)147439: |2 rvk | ||
| 245 | 1 | 0 | |a Selenium and tellurium reagents |b in chemistry and materials science |c edited by Risto S. Laitinen, Raija Oilunkaniemi |
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2019] | |
| 264 | 4 | |c © 2019 | |
| 300 | |a XV, 451 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Reagenz |0 (DE-588)4177113-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Selenverbindungen |0 (DE-588)4180908-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Chemische Synthese |0 (DE-588)4133806-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Tellurverbindungen |0 (DE-588)4184678-3 |2 gnd |9 rswk-swf |
| 653 | |a Anorganische Chemie | ||
| 653 | |a Organische Chemie | ||
| 653 | |a Tellur | ||
| 653 | |a Selen | ||
| 689 | 0 | 0 | |a Selenverbindungen |0 (DE-588)4180908-7 |D s |
| 689 | 0 | 1 | |a Tellurverbindungen |0 (DE-588)4184678-3 |D s |
| 689 | 0 | 2 | |a Reagenz |0 (DE-588)4177113-8 |D s |
| 689 | 0 | 3 | |a Chemische Synthese |0 (DE-588)4133806-6 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Laitinen, Risto |4 edt | |
| 700 | 1 | |a Oilunkaniemi, Raija |4 edt | |
| 710 | 2 | |a Walter de Gruyter GmbH & Co. KG |0 (DE-588)10095502-2 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-110-52934-0 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-110-52810-7 |
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| 856 | 4 | 2 | |m X:MVB |u http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110527940&searchTitles=true |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-030785410 | |
Datensatz im Suchindex
| DE-19_call_number | 1801/VK 7716 L189 |
|---|---|
| DE-19_location | 85 |
| DE-BY-UBM_katkey | 5746154 |
| DE-BY-UBM_media_number | 41626493030012 |
| _version_ | 1823056779349590016 |
| adam_text | CONTENTS
PREFACE
*
V
LIST
OF
CONTRIBUTING
AUTHORS
*
XIII
RISTO
S.
LAITINEN,
RAIJA
OILUNKANIEMI
AND
TRISTRAM
CHIVERS
1
INTRODUCTION
OF
SELENIUM
AND
TELLURIUM
INTO
REACTION
SYSTEMS
*
1
1.1
1.2
1.2.1
1.2.2
1.2.3
1.2.4
1.2.5
1.2.6
1.2.7
1.2.8
1.2.9
1.2.10
1.3
1.3.1
1.3.2
1.3.3
1.3.4
1.3.5
1.3.6
1.3.7
1.3.8
1.3.9
1.3.10
1.3.11
1.4
INTRODUCTION
*
1
ELEMENTAL
SELENIUM
*
2
GENERAL
*
2
ANIONIC
SELENIDES
AND
THEIR
DERIVATIVES
*
3
SELENIUM
HALOGENIDES
*
6
HETEROCYCLIC
SELENIUM
SULFIDES
*
6
HOMOPOLYATOMIC
SELENIUM
CATIONS
*
8
TRIORGANYLPHOSPINE
SELENIDES
*
8
GRIGNARD
AND
ORGANYLLITHIUM
REAGENTS
*
8
SELENIUM
AND
HEAVY
GROUP
14
REAGENTS
*
9
SELENIUM-BORON
CHEMISTRY
*
10
TRANSITION
METAL
SELENIDES
*
11
ELEMENTAL
TELLURIUM
*
12
GENERAL
*
12
ANIONIC
TELLURIDES
*
12
DERIVATIVES
OF
ANIONIC
TELLURIDES
*
14
TELLURIUM-CONTAINING
CHALCOGEN
RINGS
*
14
HOMOPOLYATOMIC
TELLURIUM
CATIONS
*
15
TRIORGANYLPHOSPHINE
TELLURIDES
*
15
GRIGNARD
AND
ORGANYLLITHIUM
REAGENTS
*
16
SILANE-
AND
GERMANETELLONES
*
16
GROUP
13
CHEMISTRY
WITH
TELLURIUM
*
16
TITANOCENE
CHEMISTRY
*
18
SOLID-STATE
AND
HYDROTHERMAL
REACTIONS
*
19
SUMMARY
*
19
REFERENCES
*
20
TRISTRAM
CHIVERS
AND
RISTO
5.
LAITINEN
2
SELENIUM-
AND
TELLURIUM-HALOGEN
REAGENTS
*
27
2.1
2.2
2.2.1
2.2.2
2.2.3
SCOPE
AND
INTRODUCTION
*
27
BINARY
CHALCOGEN-HALOGEN
REAGENTS
*
28
SELENIUM
TETRAHALIDES
*
28
SELENIUM
OXYCHLORIDE
*
29
SELENIUM
DIHALIDES
*
31
VIII
*
CONTENTS
2.2.4
2.2.5
2.2.6
2.2.7
2.3
2.3.1
2.3.2
2.3.3
2.3.4
2.4
DISELENIUM
DIHALIDES
*
34
MIXTURES
OF
SELENIUM
HALIDES
*
36
TELLURIUM
TETRAHALIDES
*
36
TELLURIUM
DIHALIDES
AND
DITELLURIUM
DIHALIDES
*
41
ORGANOCHALCOGEN-HALOGEN
REAGENTS
*
44
ORGANOSELENIUM
AND
TELLURIUM
TRIHALIDES
*
44
DIORGANO-SELENIUM
AND
-TELLURIUM
DIHALIDES
*
46
MIXED-VALENT
STATE
COMPOUNDS
RTEX
2
TER
*
48
ORGANO
SELENIUM
AND
-TELLURIUM
MONOHALIDES
*
48
CONCLUSIONS
*
51
REFERENCES
*
52
ALEXANDRA
POP,
CRISTIAN
SILVESTRU
AND
ANCA
SILVESTRU
3
ORGANOSELENIUM
AND
ORGANOTELLURIUM
COMPOUNDS
CONTAINING
CHALCOGEN
OXYGEN
BONDS
IN
ORGANIC
SYNTHESIS
OR
RELATED
PROCESSES
*
61
3.1
3.2
3.2.1
3.2.2
3.2.3
3.3
3.3.1
3.3.2
3.3.3
3.4
INTRODUCTION
*
61
ORGANOSELENIUM
COMPOUNDS
*
64
ORGANOSELENIUM(LL)
COMPOUNDS
*
64
ORGANOSELENIUM(IV)
COMPOUNDS
*
69
ORGANOSELENIUM(VI)
COMPOUNDS
*
84
ORGANOTELLURIUM
COMPOUNDS
*
91
ORGANOTELLURIUM(LL)
COMPOUNDS
*
91
ORGANOTELLURIUM(IV)
COMPOUNDS
*
92
ORGANOTELLURIUM(VI)
COMPOUNDS
*
107
CONCLUSION
AND
OUTLOOK
*
109
ABBREVIATIONS
*
110
REFERENCES
*
111
TRISTRAM
CHIVERS
AND
RISTO
S.
LAITINEN
4
SELENIUM-
AND
TELLURIUM-NITROGEN
REAGENTS
*
123
4.1
4.2
4.2.1
4.2.2
4.2.3
4.3
4.3.1
4.3.2
4.4
4.5
4.6
SCOPE
AND
INTRODUCTION
*
123
BINARY
SELENIUM-NITROGEN
AND
TELLURIUM-NITROGEN
REAGENTS
*
124
NEUTRAL
SPECIES
*
124
CATIONS
*
127
ANIONS
*
127
CHALCOGEN-NITROGEN
HALIDES
*
127
TERNARY
SELENIUM-NITROGEN
HALIDES
*
127
IMIDO
CHALCOGEN
HALIDES
*
129
E(NSO)
2
REAGENTS
(E
---
SE,
TE)
*
130
SELENIUM/TELLURIUM-NITROGEN-SILICON
REAGENTS
*
131
CHALCOGENYLNITROSYLS
ARN=SE
*
134
CONTENTS
*
IX
4.7
4.7.1
4.7.2
4.7.3
4.7.4
4.8
4.9
4.10
4.11
CHALCOGEN(IV)
DIIMIDES
*
135
SYNTHESIS,
STRUCTURES
AND
APPLICATIONS
IN
ORGANIC
SYNTHESIS
*
135
THERMAL
DECOMPOSITION
*
136
INSERTION
AND
CYCLOADDITION
REACTIONS
*
137
REACTIONS
WITH
NUCLEOPHILES
AND
ELECTROPHILES
*
138
TRIS(TERT-BUTYLIMIDO)TELLURITE
DIANION
*
138
CHALCOGEN(LL)
AMIDES
AND
DIAMIDES
*
139
RADICAL
CHEMISTRY
*
141
CONCLUSIONS
*
143
REFERENCES
*
143
GUOXIONG
HUA
AND
J.
DEREK
WOOLLINS
5
ORGANOPHOSPHORUS-SELENIUM/TELLURIUM
REAGENTS:
FROM
SYNTHESIS
TO
APPLICATIONS
*
151
5.1
5.2
5.2.1
5.2.2
5.3
5.3.1
5.3.2
5.4
5.4.1
5.4.2
5.4.3
5.4.4
5.4.5
5.5
5.5.1
5.5.2
5.6
5.7
5.8
INTRODUCTION
*
151
BINARY
PHOSPHORUS-SELENIUM/TELLURIUM
SPECIES
*
152
BINARY
PHOSPHORUS-SELENIUM
SPECIES
*
152
BINARY
PHOSPHORUS-TELLURIUM
SPECIES
*
153
ORGANOPHOSPHORUS(LLL)-SELENIUM/TELLURIUM
COMPOUNDS
*
153
ORGANOPHOSPHORUS(LLL)-SELENIUM
COMPOUNDS
*
153
ORGANOPHOSPHORUS(LLL)-TELLURIUM
COMPOUNDS
*
155
PHOSPHORUS
(V)-SELENIDES/TELLURIDES
*
156
TRIORGANYLPHOSPHINE
SELENIDES
*
156
PHOSPHINOSELENOIC
CHLORIDES
AND
DERIVATIVES
*
157
PHOSPHINOSELENOIC
ACIDS
AND
DERIVATIVES
*
162
0,0,0-TRIORGANORYLPHOSPHOROSELENOATES
(RO)
3
P=SE
*
163
TERTIARY
PHOSPHINE
TELLURIDES
R
3
P=TE
*
164
DISELENOPHOSPHINATES/DITELLUROPHOSPHINATES
*
166
DISELENOPHOSPHINATES
*
166
TELLUROPHOSPHINITES
AND
DITELLUROPHOSPHINATES
*
172
DISELENAPHOSPHETANE
DISELENIDES
AND
WOOLLINS
*
REAGENT
*
173
PHOSPHORUS-SELENIUM/TELLURIUM
AMIDES
AND
IMIDES
*
185
OUTLOOK
*
195
REFERENCES
*
196
JAMIE
S.
RITCH
6
SYNTHESIS
AND
COORDINATION
CHEMISTRY
OF
CYCLIC
SELENO-
AND
TELLUROUREAS
*
207
6.1
6.2
6.3
INTRODUCTION
*
207
STRUCTURAL
VARIETY
OF
CYCLIC
HCUS
*
208
SYNTHESIS
OF
HEAVY
CHALCOGENOUREAS
*
209
X
CONTENTS
6.3.1
DIRECT
CHALCOGENATION
*
209
6.3.2
DEPROTONATION-CHALCOGENATION
*
209
6.3.3
ONE-POT
REACTIONS
*
213
6.3.4
OTHER
METHODS
*
214
6.4
GENERAL
PROPERTIES
OF
HCUS
*
215
6.5
77
SE
AND
125
TE
NMR
SPECTROSCOPIC
PROPERTIES
*
217
6.6
COORDINATION
CHEMISTRY
*
217
6.6.1
P-BLOCK
(GROUPS
13-16)
-----
219
6.6.2
GROUP
12
----
222
6.6.3
GROUP
11
-----
224
6.6.4
GROUP
10
----
231
6.6.5
GROUP
9
-----
233
6.6.6
GROUP
8
-----
235
6.6.7
GROUP
6
-----
235
6.7
CONCLUSIONS
AND
OUTLOOK
*
236
ABBREVIATIONS
*
237
REFERENCES
*
237
FATEH
V.
SINGH
AND
THOMAS
WIRTH
7
SELENIUM
AND
TELLURIUM
ELECTROPHILES
IN
ORGANIC
SYNTHESIS
*
243
7.1
INTRODUCTION
*
243
7.2
SELENIUM
ELECTROPHILES
*
243
7.2.1
SELENENYLATION
REACTIONS
*
244
7.2.2
SELENENYLATION
OF
ALIPHATIC
C-H
BONDS
*
256
7.2.3
SELENENYLATION
OF
AROMATIC
C-H
BONDS
*
258
7.2.4
CYCLIZATIONS
*
264
7.2.5
METAL-CATALYZED
COUPLING
REACTIONS
*
269
7.2.6
CARBENE
INSERTION
REACTION
*
273
7.2.7
REARRANGEMENTS
*
273
7.2.8
CATALYTIC
REACTIONS
*
275
7.3
CHIRAL
SELENIUM
ELECTROPHILES
IN
STEREOSELECTIVE
REACTIONS
*
7.4
TELLURIUM
ELECTROPHILES
IN
ORGANIC
SYNTHESIS
*
284
REFERENCES
*
289
PETER
C.
HO,
JIN
WANG
AND
IGNACIO
VARGAS-BACA
8
REAGENTS
THAT
CONTAIN
SE-H
OR
TE-H
BONDS
*
301
8.1
INTRODUCTION
*
301
8.2
CHALCOGEN
DIHYDRIDES
(H
2
CH)
*
301
8.3
SODIUM
HYDROCHALCOGENIDES
(NAHCH)
*
303
8.4
LITHIUM
DIHYDROSELENOXO
ALUMINATE
LI(AIH
2
SE)
*
305
8.5
CHALCOGENOLS
RCHH
*
305
281
CONTENTS
*
XI
8.6
8.7
MONOCHALCOGENOCARBOXYLIC
ACIDS
RC(O)CHH
*
306
N,N-DIMETHYL
CHALCOGENOCARBAMIC
ACIDS
ME
2
NC(0)CHH
*
308
REFERENCES
*
309
CLAUDIO
SANTI,
LUCIA
CAPOCCIA
AND
BONIFACIO
MONTI
9
ZINC-SELENIUM
REAGENTS
IN
ORGANIC
SYNTHESIS
*
315
9.1
9.2
9.2.1
9.2.2
9.2.3
9.2.4
INTRODUCTION
*
315
OXIDATIVE
ZINC
INSERTION
IN
SE-SE
AND
SE-X
BOND
*
316
SYNTHESIS
AND
REACTIVITY
OF
RSEZNSER
COMPLEXES
*
316
A
VERSATILE
AND
RECYCLABLE
BIPHASIC
SYSTEM
*
320
SYNTHETIC
APPLICATIONS
OF
TMEDA
STABILIZED
PHSEZNSEPH
*
322
PHSEZN-HALIDES
AND
THE
UNEXPECTED
ON-WATER
REACTIVITY
*
323
REFERENCES
*
327
ALEXANDER
M.
BOLGAR
AND
JOHN
F.
CORRIGAN
10
RECENT
ADVANCES
IN
THE
SELF-ASSEMBLY
OF
POLYNUCLEAR
METAL-SELENIUM
AND
-TELLURIUM
COMPOUNDS
FROM
14-16
REAGENTS
*
331
10.1
10.2
10.2.1
10.2.2
10.2.3
10.2.4
10.3
10.3.1
10.3.2
10.4
INTRODUCTION
*
331
SILANE
ELIMINATION
METHODS
*
332
BIS(TRIMETHYLSILYL)CHALCOGENIDE
REAGENTS
*
333
ORGANIC
TRIMETHYLSILYLCHALCOGENIDES
*
337
METAL
CHALCOGENIDE/CHALCOGENOLATE
CLUSTERS
*
345
METAL
TRIMETHYLSILYLCHALCOGENOLATES
*
351
COORDINATION
OF
14-16
LIGANDS
*
356
CHALCOGENIDOTETRELATES
*
356
ORGANOTETREL
CHALCOGENIDES
*
366
SUMMARY
-----
370
NOTES
*
371
REFERENCES
*
371
VIMAL
K.
JAIN
AND
G.
KEDARNATH
11
APPLICATIONS
OF
METAL
SELENIUM/TELLURIUM
COMPOUNDS
IN
MATERIALS
SCIENCE
*
383
11.1
11.2
11.2.1
11.2.2
11.2.3
11.2.4
11.2.5
11.3
INTRODUCTION
*
383
SYNTHESIS
OF
CHALCOGENOLATE/CHALCOGENIDE
COMPLEXES
*
385
REACTIONS
OF
NUCLEOPHILIC
CHALCOGEN
REAGENTS
WITH
METAL
SALTS
*
385
OXIDATIVE
ADDITION
OF
DICHALCOGENIDES
*
386
LIGAND-EXCHANGE
REACTIONS
*
388
CHALCOGENOLYSIS
METHOD
*
389
INSERTION
OF
CHALCOGEN
INTO
M-C
BOND
*
389
TRANSITION
METAL
CHALCOGENOLATE/CHALCOGENIDE
CLUSTERS
*
390
XII
*
CONTENTS
11.4
11.4.1
11.4.2
11.4.3
11.4.4
11.4.5
11.4.6
11.4.7
11.4.8
11.4.9
11.5
11.5.1
11.5.2
11.5.3
11.6
11.7
TRANSITION
METAL
CHALCOGENOLATE
PRECURSORS
FOR
METAL
CHALCOGENIDES
*
397
GROUP
4
(TI,
ZR,
HF)
CHALCOGENIDES
*
397
GROUP
5
(V,
NB,
TA)
CHALCOGENIDES
-----
398
GROUP
6
(CR,
MO,
W)
CHALCOGENIDE
MATERIALS
*
399
GROUP
7
(MN,
TC,
RE)
CHALCOGENIDES
*
399
GROUP
8
(FE,
RU,
OS)
CHALCOGENIDES
-----
400
GROUP
9
(CO,
RH,
IR)
CHALCOGENIDES
-----
401
GROUP
10
(NI,
RD,
PT)
CHALCOGENIDES
-----
402
GROUP
11
(CU,
AG,
AU)
CHALCOGENIDES
-----
404
GROUP
12
(ZN,
CD,
HG)
CHALCOGENIDES
*
407
MAIN
GROUP
CHALCOGENOLATES
AS
PRECURSORS
FOR
METAL
CHALCOGENIDES
*
411
GROUP
13
CHALCOGENIDES
*
411
GROUP
14
CHALCOGENIDES
*
413
GROUP
15
CHALCOGENIDES
-----
416
F-BLOCK
METAL
CHALCOGENOLATES
AS
PRECURSORS
FOR
METAL
CHALCOGENIDES
*
420
TERNARY
METAL
CHALCOGENIDES
-----
421
ABBREVIATIONS
-----
427
REFERENCES
-----
427
INDEX
*
445
|
| any_adam_object | 1 |
| author2 | Laitinen, Risto Oilunkaniemi, Raija |
| author2_role | edt edt |
| author2_variant | r l rl r o ro |
| author_facet | Laitinen, Risto Oilunkaniemi, Raija |
| building | Verbundindex |
| bvnumber | BV045399286 |
| classification_rvk | VK 7716 VK 7717 |
| ctrlnum | (OCoLC)1091669099 (DE-599)DNB1150716096 |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV045399286 |
| illustrated | Illustrated |
| indexdate | 2025-02-03T17:57:29Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783110527940 3110527944 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030785410 |
| oclc_num | 1091669099 |
| open_access_boolean | |
| owner | DE-29T DE-19 DE-BY-UBM DE-11 |
| owner_facet | DE-29T DE-19 DE-BY-UBM DE-11 |
| physical | XV, 451 Seiten Illustrationen, Diagramme |
| publishDate | 2019 |
| publishDateSearch | 2019 |
| publishDateSort | 2019 |
| publisher | De Gruyter |
| record_format | marc |
| spellingShingle | Selenium and tellurium reagents in chemistry and materials science Reagenz (DE-588)4177113-8 gnd Selenverbindungen (DE-588)4180908-7 gnd Chemische Synthese (DE-588)4133806-6 gnd Tellurverbindungen (DE-588)4184678-3 gnd |
| subject_GND | (DE-588)4177113-8 (DE-588)4180908-7 (DE-588)4133806-6 (DE-588)4184678-3 |
| title | Selenium and tellurium reagents in chemistry and materials science |
| title_auth | Selenium and tellurium reagents in chemistry and materials science |
| title_exact_search | Selenium and tellurium reagents in chemistry and materials science |
| title_full | Selenium and tellurium reagents in chemistry and materials science edited by Risto S. Laitinen, Raija Oilunkaniemi |
| title_fullStr | Selenium and tellurium reagents in chemistry and materials science edited by Risto S. Laitinen, Raija Oilunkaniemi |
| title_full_unstemmed | Selenium and tellurium reagents in chemistry and materials science edited by Risto S. Laitinen, Raija Oilunkaniemi |
| title_short | Selenium and tellurium reagents |
| title_sort | selenium and tellurium reagents in chemistry and materials science |
| title_sub | in chemistry and materials science |
| topic | Reagenz (DE-588)4177113-8 gnd Selenverbindungen (DE-588)4180908-7 gnd Chemische Synthese (DE-588)4133806-6 gnd Tellurverbindungen (DE-588)4184678-3 gnd |
| topic_facet | Reagenz Selenverbindungen Chemische Synthese Tellurverbindungen |
| url | https://www.degruyter.com/doc/cover/9783110527940.jpg http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110527940&searchTitles=true http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030785410&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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